 |
 |
 |
 |
 |
 |
||
 |
 |
 |
 |
 |
| 1 | 1/1 | 返回列表 |
| 查看: 714 | 回復: 0 | ||
2010210144新蟲 (小有名氣)
|
[求助]
雙疏性
|
|
Supporting Online Material for Candle Soot as a Template for a Transparent Robust Superamphiphobic Coating Xu Deng, Lena Mammen, Hans-Jürgen Butt, Doris Vollmer* *To whom correspondence should be adddressed. E-mail: vollmerd@mpip-mainz.mpg.de Published 1 December 2011 on Science Express DOI: 10.1126/science.1207115 This PDF file includes: Materials and Methods SOM Text Figs. S1 to S11 Tables S1 and S2 References Captions for Movies S1 to S3 Other Supporting Online Material for this manuscript includes the following: (available at www.sciencemag.org/cgi/content/full/science.1207115/DC1) Movies S1 to S3 Materials and Methods Materials Tetraethoxysilane (TES) (Acros Organics, 98%), ammonia (VWR, 28%), (tridecafluoro- 1,1,2,2-tetrahydrooctyl)-1-trichlorosilane (Sigma Aldrich, 97%), milli-Q water, diiodomethane, ethylene glycol, penaut oil (commercial), olive oil (commercial), hexadecane and tetradecane were used without further purification. Characterization The morphology of the soot particles and the coating were characterized by Scanning Electron Microscopy (low voltage LEO 1530 Gemini, Germany, and SU8000, Hitachi, Japan). The samples were prepared on a silicon wafer and investigated without further treatment. After calcination the hollow silica networks were imaged by Transmission Electron Microscopy (FEI, 200 kV). Static, advancing, receding, and roll off angles were measured with a contact angle meter, Dataphysics OCA35 (Data Physics Instruments GmbH, Germany). Transmission was measured using an ultraviolet-visible spectrometer (Lambda 900, Perkin Elmer) in double-beam mode, using an uncovered glass slide as a reference. High speed movies were taken with a high speed camera (Photron, Fastcam SA1). Methods Chemical vapor deposition of TES: The soot coated substrates (glass or silicon) were placed in a desiccator together with two open glass vessels containing about 2 ml of tetraethoxysilane (TES) and aqueous ammonia solution, respectively (Fig. S1). The desiccator was closed again and chemical vapor deposition (CVD) of TES was carried out for 24 h, if not stated otherwise. Similar to a Stöber reaction (33), silica is formed by hydrolysis and condensation of TES catalysed by ammonia (34). Fig. S1. Sketch of a desiccator together with the soot coated substrate (middle) and two glass vessels, containing tetraethoxysilane (TES) and ammonia solution (NH3), respectively. Silica shells prepared by the Stöber reaction are nano-porous. During calcination, carbon (in general a polymer) cores thermally degrade and carbon diffuses through the silica shell (35-37). After calcination of the fractal-like carbon/silica network at 600°C for 2 h in air, the hydrophilic silica coating is hollow. To transform it into a superamphiphobic coating chemical vapor deposition (CVD) of a semi-fluorinated silane on the films was performed. Therefore, the coated substrate and an open glass vessel containing about 0.1 |
回復此樓» 猜你喜歡
0703化學調(diào)劑，求導師收
已經(jīng)有3人回復
-
生物學學碩求調(diào)劑
已經(jīng)有6人回復
-
305分求調(diào)劑（食品工程）
已經(jīng)有7人回復
-
材料與化工考研調(diào)劑
已經(jīng)有5人回復
-
299求調(diào)劑
已經(jīng)有6人回復
-
材料292調(diào)劑
已經(jīng)有5人回復
-
085404電子信息284分求調(diào)劑
已經(jīng)有4人回復
-
收08調(diào)劑生
已經(jīng)有3人回復
-
081700 調(diào)劑 267分
已經(jīng)有9人回復
-
293求調(diào)劑
已經(jīng)有5人回復
相關(guān)版塊跳轉(zhuǎn)
我要訂閱樓主 2010210144 的主題更新
| 1 | 1/1 | 返回列表 |
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 293求調(diào)劑 +5 | 加一一九 2026-03-24 | 5/250 |
|
|---|---|---|---|---|
|
[考研] 求調(diào)劑 +5 | 研研，接電話 2026-03-24 | 6/300 |
|
|
|
[考研] 306求0703調(diào)劑一志愿華中師范 +9 | 紙魚ly 2026-03-21 | 10/500 |
|
|
|
[考研] 298-一志愿中國農(nóng)業(yè)大學-求調(diào)劑 +11 | 手機用戶 2026-03-17 | 12/600 |
|
|
|
[考研] 求材料，環(huán)境專業(yè)調(diào)劑 +3 | 18567500178 2026-03-18 | 3/150 |
|
|
|
[考研] 291求調(diào)劑 +8 | hhhhxn.. 2026-03-23 | 8/400 |
|
|
|
[考研] 材料專碩找調(diào)劑 +3 | 哈哈哈吼吼吼哈 2026-03-23 | 3/150 |
|
|
|
[考研] 284求調(diào)劑 +3 | yanzhixue111 2026-03-23 | 6/300 |
|
|
|
[考研] 化學308分求調(diào)劑 +3 | 你好明天你好 2026-03-23 | 3/150 |
|
|
|
[考研] 一志愿華中農(nóng)業(yè)071010，總分320求調(diào)劑 +5 | 困困困困坤坤 2026-03-20 | 6/300 |
|
|
|
[考研] 287求調(diào)劑 +8 | 晨昏線與星海 2026-03-19 | 9/450 |
|
|
|
[考研] 求調(diào)劑院校信息 +6 | CX 330 2026-03-21 | 6/300 |
|
|
|
[考研] 269專碩求調(diào)劑 +6 | 金恩貝 2026-03-21 | 6/300 |
|
|
|
[考研] 0805材料320求調(diào)劑 +3 | 深海物語 2026-03-20 | 3/150 |
|
|
|
[考研] 299求調(diào)劑 +6 | △小透明* 2026-03-17 | 6/300 |
|
|
|
[考研] 華東師范大學-071000生物學-293分-求調(diào)劑 +3 | 研究生何瑤明 2026-03-18 | 3/150 |
|
|
|
[考研] 308求調(diào)劑 +3 | 阿姐阿姐家啊 2026-03-18 | 3/150 |
|
|
|
[考研] 321求調(diào)劑 +9 | 何潤采123 2026-03-18 | 11/550 |
|
|
|
[考研] 求調(diào)劑 +3 | eation27 2026-03-20 | 3/150 |
|
|
|
[考研] 一志愿南理工085701環(huán)境302求調(diào)劑院校 +3 | 葵梓衛(wèi)隊 2026-03-20 | 3/150 |
|