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Chem. Soc. Rev.最新綜述:設(shè)計(jì)合成有機(jī)無機(jī)雜化膠囊及其生物技術(shù)方面的應(yīng)用
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Design and synthesis of organic–inorganic hybrid capsules for biotechnological applications Jiafu Shi,‡ab Yanjun Jiang,‡c Xiaoli Wang, a Hong Wu, ad Dong Yang, a Fusheng Pan, ad Yanlei Su ad and Zhongyi Jiang*ad a Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China. E-mail: zhyjiang@tju.edu.cn b School of Environmental Science and Engineering, Tianjin University,Tianjin 300072, China c School of Chemical Engineering and Technology, HeBei University of Technology,Tianjin 300130, China d Collaborative Innovation Center of Chemical Science and Engineering (Tianjin),Tianjin 300072, China † Electronic supplementary information (ESI) available. See DOI: 10.1039/c4cs00108g ‡ Jiafu Shi and Yanjun Jiang contributed equally. Organic–inorganic hybrid capsules, which typically possess a hollow lumen and a hybrid wall, have emerged as a novel and promising class of hybrid materials and have attracted enormous attention. In comparison to poly- meric capsules or inorganic capsules, the hybrid capsules combine the intrinsic physical/chemical properties of the organic and inorganic moieties, acquire more degrees of freedom to manipulate multiple interactions, create hierarchical structures and integrate multiple functionalities. Thus, the hybrid capsules exhibit superior mechanical strength (vs. polymeric capsules) and diverse functionalities (vs. inorganic capsules), which may give new opportunities to produce high-performance materials. Much effort has been devoted to exploring innovative and effective methods for the synthesis of hybrid capsules that exhibit desirable performance in target applications. This tutorial review firstly presents a brief description of the capsular structure and hybrid materials in nature, then classifies the hybrid capsules into molecule-hybrid capsules and nano-hybrid capsules based upon the size of the organic and inorganic moieties in the capsule wall, followed by a detailed discussion of the design and synthesis of the hybrid capsules. For each kind of hybrid capsule, the state-of-the-art synthesis methods are described in detail and a critical comment is embedded. The applications of these hybrid capsules in biotechnological areas (biocatalysis, drug delivery, etc.) have also been summarized. Hopefully, this review will offer a perspective and guidelines for the future research and development of hybrid capsules. |
Nano&Micro | 科研啊 努力啊 希望有用啊 | 材料物理與化學(xué) | 超分子與自組裝 |
納米材料 | 功能復(fù)合材料 |
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