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happy308木蟲 (正式寫手)
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[交流]
over-screening charge effect和ion confinement應(yīng)該怎么解釋?
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Extensive work was done to understand the electrode electrolyte interfaces using various simulation techniques, and it is now recognized that the ions adopt a multilayered structure at the ionic liquid/graphite (planar) electrode interface. Such behavior is described as the “over-screening charge effect":because of electrostatic interactions between ions in IL, the charge carried out by the first layer of ions adsorbed at the carbon surface exceeds the one present at the carbon surface. recent discoveries of the capacitance increase in carbon pores less than 1 nm have refocused the research efforts toward the understanding of the ion confinement in nanopores for explaining the capacitance increase when the electrolyte ion size matches the carbon pore size 最近看超電大牛Y. Gogotsi和P. Simon關(guān)于碳材料應(yīng)用于超電的綜述Capacitive Energy Storage in Nanostructured CarbonElectrolyte Systems,碰到題目中這兩個名詞,網(wǎng)上沒有找到滿意的解答,不知道應(yīng)該如何理解才是正確? |
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