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chemmtf銅蟲 (小有名氣)
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[求助]
jpc修改稿審稿意見
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| The SOMOs, and not the HOMO’s as mentioned in the article and in the caption of supplementary material, of the triplet states displayed in figure S1 and the spin density represented in figure S-3 let me think that the holes of the triplet are not correctly identified. Du to spin repolarization effects in UDFT calculation, it is very scarce that SOMO-1 represents the hole. To my experience the hole of triplet states of similar complex is borne by deeper SOMO. To remove all doubts and to follow the discussion safely, the authors have to calculate Natural Orbitals. 這篇文章不涉及三重態(tài)的自旋密度,而審稿人堅(jiān)持要做出三重態(tài)自旋密度圖,三重態(tài)自旋密度圖和三重態(tài)分子軌道圖有什么關(guān)系,在修改稿中軌道圖和自旋密度圖已做過(guò),為什么審稿人還要計(jì)算Natural Orbitals,如何計(jì)算Natural Orbitals?拜托各位了! |
木蟲 (著名寫手)
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