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Furthermore, FC4 and FC8 solids are molten and then rapidly put into liquid N2, which should afford real amorphous states. It is shown that the quenched solids have thesame emission spectra as the ground or pressed samples (Fig. 6). These findings indicate that the transformation between the amorphous and crystalline states under various external stimuli is responsible for the reversible PFC behaviour. Further inspection of the DSC curves of the ground solids reveals that the cold-crystallization temperatures (Tcc) of the ground FCn solids decreases gradually with the length of N-alkyl chains (Fig. 5b and Table 1). Based on the decreased rate of Tcc from FC1 to FC8, the Tcc values of the ground FC10 and FC12 should be at or below room temperature. This implies that changing the length of the N-alkyl chains can significantly affect the Tcc of amorphous FCn solids. |

至尊木蟲 (知名作家)
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| 此外,熔化FC4和FC8固體并迅速放入液氮,這樣可提供真實的非晶狀態(tài)。結(jié)果表明,該驟冷固體具有與研磨或受壓樣品相同的發(fā)射光譜(圖6)。這些結(jié)果表明,在各種外部刺激作用下非晶體和晶體態(tài)之間的轉(zhuǎn)變是PFC可逆行為的原因。進一步檢查研磨固體DSC曲線顯示,研磨FCN固體的冷結(jié)晶溫度(Tcc為)隨N-烷基鏈長度而逐漸減。▓D5b及表1);贔C1至FC8該Tcc的降低速率,研磨FC10和FC12的Tcc值應(yīng)等于或低于室溫。這意味著,改變N-烷基鏈的長度可以顯著影響非晶FCn固體的Tcc。 |
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