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| However, when the cross-linker concentrations are too high, the reaction activity of the cross-linker NMBA would also be high, with enough trace amounts of NMBA to facilitate cross-linking reactions and form a mesh structure (Peng, Xu, Peng, Wang, & Zheng, 2008; Pourjava, Barzegar, & Mahdavinia, 2006). The increase in cross-linking sites and crosslinking density makes the resin network distances closer and the resin hard to stretch, which result in the reduction of the volume of liquid it can hold and the reduction of swelling capacity. Considering the resin water absorbency and hydrogel state results, the cross-linker concentration was found to account for 0.04% ofthe total monomer mass at optimal experimental conditions. |
至尊木蟲 (知名作家)
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| 然而,當(dāng)交聯(lián)劑的濃度過高時,交聯(lián)劑NMBA的反應(yīng)活性將也是高的,痕量的NMBA就足以促進(jìn)交聯(lián)反應(yīng),并形成網(wǎng)狀結(jié)構(gòu)(Peng, Xu, Peng, Wang, & Zheng, 2008; Pourjava, Barzegar, & Mahdavinia, 2006)。交聯(lián)位點和交聯(lián)密度的增加,使樹脂網(wǎng)絡(luò)的距離更接近,樹脂難以伸展,導(dǎo)致可以容納液體體積的減少和溶脹能力的降低?紤]到樹脂的吸水性和水凝膠狀態(tài),發(fā)現(xiàn)在最佳實驗條件下,交聯(lián)劑濃度占單體總質(zhì)量的0.04%。 |
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