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| Thelem of1B-TPA, 2B-TPAand3B-TPAwere 467, 461 and 456 nm in CH, and 519, 527 and 529 nm in DMSO, respectively. Compared with thelin CH solutions, the lvalues in DMSO solutions red-shifted by 52, 66 and 73 nm for1B-TPA, 2B-TPAand3B-TPA, respectively. The fluorescent images of 2B-TPAdissolved in different solvents taken under irradiation at 365 nm are shown in Fig. 6. As can be seen, the fluorescence colors completely differ from each other. Thus, the emission properties of this group of molecules highly depend on the solvent polarity. |
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| 1B-TPA,2B-TPA和3B-TPA在CH中的lem分別是467,461,456 nm,在DMSO中分別為519,527和529 nm。與在CH溶液中的lem相比,1B-TPA,2B-TPA和3B-TPA的lem在DMSO溶液中分別紅移52,66和73nm。2B-TPA溶解在不同溶劑中,在365nm照射下得到的熒光圖像見圖6?梢钥吹,熒光顏色彼此完全不同。因此,這組分子的發(fā)光性能高度依賴于溶劑的極性。 |
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