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| The large bathochromic shift combined with the decreasedF might be related to the stabilization of the excited state. This behavior is frequently observed in highly polarized molecules exhibiting enlarged dipoles and charge-transfer characters in their excited states referred to as intramolecular charge-transfers (ICT). 13 Since solvent polarity had little effect on the absorption wavelengths of the compounds, their solvatochromisms might be caused by photo-induced ICT in the excited state, suggesting that the ICT excited state had a larger dipolar moment compared with the ground state, due to substantial charge redistribution. |
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| 大紅移合并F降低可能與激發(fā)態(tài)的穩(wěn)定化有關(guān)。這種現(xiàn)象經(jīng)常出現(xiàn)在高度兩極化的分子,表現(xiàn)為擴(kuò)大的偶極以及在激發(fā)態(tài)時(shí)的電荷轉(zhuǎn)移特點(diǎn),稱之為分子內(nèi)電荷轉(zhuǎn)移(ICT)。由于溶劑的極性對(duì)化合物的吸收波長的影響很小,在激發(fā)態(tài)時(shí)它們的溶劑化可能是由光誘導(dǎo)的ICT引起的,表明與研磨狀態(tài)相比,ICT激發(fā)態(tài)有較大的偶極矩,因?yàn)榇罅侩姾稍俜峙洹? |
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