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帥博士木蟲 (正式寫手)
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[交流]
大伙幫看看,這個實驗有點不敢做啊
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想?yún)⒖家黄墨I(xiàn)做溶解熱合成,但是細(xì)看實驗條件有點恐怖啊。 文獻(xiàn)鏈接:http://pubs.rsc.org/en/Content/A ... 00621a#!divAbstract 實驗部分原文:In a typical synthesis, ferrocene (0.30 g) was dissolved in acetone (30 mL). After intense sonication for 30 min, 1.50 mL of hydrogen peroxide was slowly added into the above mixture solution, which was then vigorously stirred for 30 min with magnetic stirring. After that, the precursor solution was transferred to the Teflon-lined stainless autoclave with a total volume of 50.0 mL, and then heated to and maintained at 240 °C. After 72 h, the autoclave was cooled naturally to room temperature. 先不說反應(yīng)釜能不能受這高溫。 查了下,丙酮的沸點65 °C,加熱到240°C還加了1.5mL雙氧水,實際反應(yīng)會不會爆炸? 但卻是又對他做出來的氧化鐵比較感興趣,糾結(jié)中啊。 |
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