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2014英文新書：石墨烯的光電合成、表征、特性及其應(yīng)用
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Graphene Optoelectronics Synthesis, Characterization, Properties, and Applications Author(s): Abdul Rashid bin M. Yusoff Publisher: Weinheim, Bergstr Wiley-VCH Year: 2014 Edition: 1., Auflage Language: English Pages: 296 This first book on emerging applications for this innovative material gives an up-to-date account of the many opportunities graphene offers high-end optoelectronics. The text focuses on potential as well as already realized applications, discussing metallic and passive components, such as transparent conductors and smart windows, as well as high-frequency devices, spintronics, photonics, and terahertz devices. Also included are sections on the fundamental properties, synthesis, and characterization of graphene. With its unique coverage, this book will be welcomed by materials scientists, solid-state chemists and solid-state physicists alike. Contents List of Contributors XIII Preface XIX 1 Electronic Transport and Optical Properties of Graphene 1 Klaus Ziegler, Antonio Hill, and Andreas Sinner 1.1 Introduction 1 1.2 Basic Experimental Facts 3 1.3 Models for Transport in Graphene 5 1.4 DC Conductivity 6 1.5 AC Conductivity for VeryWeak Scattering and Thermal Fluctuations 9 1.6 Plasmons 11 1.7 Discussion 13 References 14 2 Synthesis and Modification of Graphene 17 Ding Zhou, Yi Cui, and Bao-Hang Han 2.1 Synthesis of Graphene 17 2.1.1 “Top-Down” Approach 17 2.1.1.1 Micromechanical Cleavage 17 2.1.1.2 Liquid-Phase Exfoliation 18 2.1.1.3 Oxidation and Reduction 19 2.1.1.4 Exfoliation of Graphite Intercalation Compounds 21 2.1.2 “Bottom-Up” Approach 22 2.1.2.1 Chemical Vapor Deposition 22 2.1.2.2 Epitaxial Growth 24 2.1.2.3 Chemical Synthesis 25 2.2 Modification and Functionalization of Graphene 26 2.2.1 Noncovalent Modification 27 2.2.2 Covalent Modification 28 2.2.2.1 Cycloaddition 28 2.2.2.2 Free-Radical Addition 30 2.2.2.3 Substitution 31 2.2.3 Covalent Modification Based on Oxygen-Containing Groups 32 2.3 Concluding Remarks and Perspectives 33 References 34 3 Graphene for the Elaboration of Nanocomposite Films for Optoelectronic Applications 41 Mohammed Khenfouch,Mimouna Baitoul, and Malik Maaza 3.1 Introduction 41 3.2 Synthesis and Optical Characterization of Few-layered Graphene Oxide (FGO) 41 3.2.1 FGO Synthesis 42 3.2.2 Optical Characterization of FGO 42 3.2.2.1 UV–Visible Spectroscopy 42 3.2.2.2 Raman Spectroscopy 43 3.2.2.3 Photoluminescence 43 3.3 Graphene as Seed Layer for Synthesis of DLC Free-Standing Films for Ultrahigh-Intensity Laser-Based Electron/Proton Acceleration Applications 44 3.3.1 Free-Standing DLC Films Synthesis 45 3.3.2 Vibrational and Optical Characterization 47 3.3.2.1 Raman Spectroscopy 47 3.3.2.2 Optical Characterization 49 3.4 ZnO/Graphene Nanorod Composites for LED Application 51 3.4.1 ZnO/Graphene Nanocomposite Synthesis 52 3.4.2 Optical Characteristics 52 3.4.2.1 UV–Visible Spectroscopy 53 3.4.2.2 Raman Spectroscopy 53 3.4.2.3 Photoluminescence 55 3.5 Conclusions 56 Acknowledgments 57 References 57 4 Metallic and Passive Components 63 Mohd Asri bin Mat Teridi and A. Rashid bin Mohd Yusoff 4.1 Introduction 63 4.2 History of Graphene 64 4.3 Applications 65 4.3.1 Transparent, Conductive, and Flexible Electronics 65 4.3.2 Flexible SmartWindows and Bistable Displays 73 4.3.3 Light-Emitting Devices 77 4.3.4 Touch Panels 79 4.3.5 Photovoltaic Devices 82 4.3.5.1 Heterojunction Solar Cells 82 …………………… 9 Graphene: Manipulate TerahertzWaves 209 Yixuan Zhou, Xinlong Xu, Haiming Fan, Mei Qi, Jiayuan Li, Jintao Bai, and Zhaoyu Ren 9.1 Introduction 209 9.2 THz Properties of Graphene 210 9.2.1 Intraband-Transition-Dependent THz Conductivity 210 9.2.2 THz Spectroscopy and THz Imaging for Probing Graphene Properties 212 9.2.3 THz Spectroscopy of Multilayer Graphene 214 9.2.4 Magnetooptic Property of Graphene in the THz Region 216 9.2.5 THz Responses of Other Graphene-Based Materials 218 9.3 Proof-of-Concept Graphene Devices 220 9.3.1 Electrooptic Modulation 221 9.3.2 Magnetooptic Modulation 222 9.3.3 All-Optic Modulation 224 9.4 Advanced THzWave Manipulation: Graphene Plasmons and Metamaterials 225 9.4.1 Graphene THz Plasmons 225 9.4.2 Graphene Coupling to THz Metamaterials 228 9.5 Conclusions and Perspective 229 Acknowledgments 230 References 230 10 Chemical and Biosensors Based on Graphene Materials 235 Perry T. Yin, Tae-Hyung Kim, Jeong-Woo Choi, and Ki-Bum Lee 10.1 Introduction 235 10.2 Graphene-Based Electronic Sensors 236 10.2.1 Electronic Chemical Sensors 237 10.2.2 Electronic Biosensors 241 10.3 Graphene-Based Electrochemical Sensors 243 10.3.1 Electrochemical Chemical Sensors 244 10.3.2 Electrochemical Biosensors 247 10.4 Graphene-Based Optical Sensors 250 10.4.1 Optical Chemical Sensors 251 10.4.2 Optical Biosensors 252 10.5 Conclusion 254 Acknowledgments 255 Abbreviations 255 References 256 Index 261 |
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