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The flexible ligand 1,3-bis(1,2,4-triazol-1-ylmethyl)benzene (mbtz) was synthesized according to the literature method [20]. Cd(BF4)2Æ6H2O, CdCl2 and CdBr2 were analytical grade reagents from Aldrich. All other reagents and solvents employed were commercially available and used as received without further purification. The C, H, N microanalyses were carried out with a Perkin-Elmer 240C analyser.IR spectra were obtained for KBr pellets on a Nicolet 170SX FT-IR spectrophotometer in the 4000– 400 cm1 region. The luminescence measurements were carried out in the solid state at room temperature and the spectra were collected with a PerkinElmer LS50B spectrofluorimeter. |
銅蟲(chóng) (小有名氣)
銅蟲(chóng) (小有名氣)
| 根據(jù)文獻(xiàn)[20]方法合成靈活配體1,3-二(1,2,4-三氮唑-1-甲基)苯(mbtz)。 Cd(BF4)2和AElig;6H2O, CdCl2 and CdBr2 用的是Aldrich中的分析級(jí)試劑。所有其他試劑和溶劑都是市場(chǎng)上可以買(mǎi)到的,并且直接使用不需要進(jìn)一步純化。對(duì)于C/H/N元素的微量分析用的是 Perkin-Elmer 240C 型號(hào)的分析儀。紅外光譜用的溴化鉀片參照 Nicolet 170SX FT-IR 紅外分光光度儀在4000-400cm1處出峰。 |
銀蟲(chóng) (小有名氣)
銅蟲(chóng) (小有名氣)
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