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Chem Rev關(guān)于超分子化學(xué)最新綜述兩篇
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第一篇是出自于華東理工大學(xué)田禾教授之手, 主要是介紹了光響應(yīng)性主客體功能系統(tǒng),其中主要介紹了超分子主客體體系, 同時(shí)還對光響應(yīng)性超分子系統(tǒng)的響應(yīng)性機(jī)理進(jìn)行了應(yīng)用闡述?傄梦墨I(xiàn)291篇。 1. Introduction 2. Photocontrollable Capture and Release of Guest Molecules from Host Molecules 2.1. Single-Molecule Hosts 2.1.1. Single-Molecule Hosts Functionalized with Photoactive Units 2.1.2. Single-Molecule Hosts for Photoresponsive Guest Molecules 2.2. Multicomponent Supramolecular Hosts 2.2.1. Supramolecular Cages and Capsules Assembled by Photoactive Components 2.2.2. Supramolecular Cages or Capsules for Photoresponsive Guest Molecules 3. Photoresponsive Rotaxane, Catenanes, and Pseudorotaxanes as Light-Driven Molecular Machines 3.1. Light-Responsive Mechanical Motion from Photoinduced Electron Transfer 3.1.1. Photoinduced Electron Transfer in Pseudorotaxanes 3.1.2. Photoinduced Electron Transfer in Rotaxanes and Catenanes 3.2. Light-Responsive Mechanical Motion Powered by Photoisomerization 3.2.1. Photoinduced Trans–Cis Isomerization of Azobenzene and Stilbene 3.2.2. Photoinduced E/Z Isomerization of Fumaramide 3.2.3. Photoinduced Ring-Open/Close Isomerization of Spiropyran 3.3. Light-Responsive Mechanical Motion Powered by Excited-State Changes 3.4. Light-Responsive Mechanical Motion Powered by Photoheterolysis 4. Photoresponsive Supramolecular Polymers and Their Assemblies 4.1. Supramolecular Interactions in the Main Chain 4.1.1. Photoswitching between Monomer/Oligomer and Supramolecular Polymers 4.1.2. Covalent/Noncovalent Bond Transitions in Linear Supramolecular Polymers 4.2. Supramolecular Interactions in the Side Chain 4.3. Supramolecular Complexations as Cross-Linkers between Branched Polymer Chains 4.4. Photoresponsive Supramolecular Micelles, Vesicles and Other Assemblies 5. Photoresponsive Host–Guest System on Surfaces 5.1. Photoresponsive Host–Guest Systems Immobilized on Nanoparticles 5.2. Photoresponsive Host–Guest Systems Organized at Planar Surfaces 5.3. Photoresponsive Host–Guest Systems Immobilized on Porous Materials 6. Summary 第二篇出自UT的Eric V. Anslyn之手, 該綜述對超分子化學(xué)在分析化學(xué)中的應(yīng)用進(jìn)行了闡述?傄梦墨I(xiàn)286篇。 1. Introduction: Definition of Supramolecular Analytical Chemistry 1.1. Analytical Chemistry and Sensors 1.2. Dynamic Interactions and Molecular Recognition 2. General Principles of Sensor Design 2.1. Direct Sensing vs Indicator Displacement Assay 2.1.1. Direct Sensing 2.1.2. Indicator Displacement Assay 2.2. Single Analyte Sensing vs Differential Sensing 2.2.1. Single Analyte Sensing 2.2.2. Differential Sensing 2.3. Types of Sensors 2.3.1. Detection Method 2.3.2. Origin 2.3.3. Structure 3. Single Analyte Sensing 3.1. Synthetic Receptors for Sensing 3.1.1. Direct Sensing 3.1.2. Indicator Displacement Assay 3.2. Dynamic Assembly for Sensing 3.2.1. Ion Pairing Interaction 3.2.2. π–π Interaction 3.2.3. Amphiphilic Interaction 3.2.4. Reversible Covalent Interaction 4. Differential Sensing 4.1. Cations 4.2. Anions 4.3. Small Neutral Molecules 4.4. Proteins, Cells, and Bacteria 5. Chirality Sensing 5.1. Enantioselective IDA 5.2. Direct Sensing 5.2.1. Synthetic Receptors 5.2.2. Self-Assembled Receptors 6. Conclusions and Future Perspectives 上述兩篇綜述對于新入行的同僚會(huì)有極大幫助 |
MOF的未來 | Book & Review | 超分子與自組裝 | 功能復(fù)合材料 |
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