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[求助]
維普求助，謝謝！ 已有1人參與
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wym-11 碳譜數據如下 13.7,16.3,17.7,18.3,18.6,23.5,23.8,24.0,26.1,26.2,28.4,30.9,32.6,32.9,33.2,34.1,37.1,40.0,40.1,41.8,42.3,43.6,46.3,47.1,47.7,48.3,50.0,61.4,64.6,67.1,69.3,70.0,70.4,71.0,72.7,72.9,73.2,74.0,74.1,74.8,75.4,76.6,77.3,78.1,78.4,78.8,82.1,95.7,102.9,105.0,106.8,123.0,144.3,176.7 溶劑 吡啶 |
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compound 5 相似度:98.1% Chemistry of Natural Compounds 2005 41 194-199 TRITERPENE GLYCOSIDES FROM Kalopanax septemlobum.1. GLYCOSIDES A, B, C, F, G1, G2, I2, H, AND J FROM LEAVES OF Kalopanax septemlobum VAR. maximowichiiINTRODUCED TO CRIMEA V. I. Grishkovets, D. A. Panov,V. V. Kachala, and A. S. Shashkov Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 2 . hederoside G 相似度:98.1% Chemistry of Natural Compounds 1990 26 663-666 TRITERPENE GLYCOSIDES OF Hedera taurica VI. STRUCTURES OF HEDEROSIDES G, Hi, H2, AND I FROM THE BERRIES OF CRIMEAN IVY V. I. Grishkovets, A. A. Loloiko,A. S. Shashkov, and V. Ya. Chirva Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 3 . 3-O-α-L-arabinopyranosyl-28-O-α-L-rhamnopyranosyl-(1→4)-O-β-D-glucopyranosyl-(1→6)-O-β-D-glucopyranosyl ester of hederagenin 相似度:98.1% Chinese Joumal of Experimental Traditional Medical Fomulae 2011 17 92-96 Chemical Constituents from Kalopanax septemlobus FAN Yan-jun, CHENG Dong-yan, WANG Li-shu Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 4 . pericarpsaponin PJ3 C53H86O22 相似度:96.2% Chemical & Pharmaceutical Bulletin 1991 39 865-870 Studies on the Constituents of the Bark of Kalopanax pictus NAKAI Kazuko SANO,Shuichi SANADA,Yoshiteru IDA and Junzo SHOJI Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 5 . glycoside H1 相似度:96.2% Chemistry of Natural Compounds 2006 42 61-66 TRITERPENE GLYCOSIDES FROM Kalopanax septemlobum.VII. MINOR GLYCOSIDES FROM STEMS OF Kalopanax septemlobumVAR. maximowiczii AND Kalopanax septemlobum VAR. typicum D. A. Panov, V. I. Grishkovets, V. V. Kachala, and A. S. Shashkov Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 6 . Glycoside I2 相似度:96.2% Chemistry of Natural Compounds 2006 42 182-185 TRITERPENE GLYCOSIDES FROM Cussonia paniculata.III. STRUCTURE OF GLYCOSIDES I1, I2, J1a, J1b, J2, K, L1, AND L2 FROM C. paniculata LEAVES I. I. Dovgii, V. I. Grishkovets, V. V. Kachala and A. S. Shashkov Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 7 . HCSt-B 相似度:96.2% Chemistry of Natural Compounds 2005 41 48-51 ARJUNOLIC ACID DERIVATIVE GLYCOSIDE FROM THE STEMS OF Hedera colchica V. Mshvildadze, O. Kunert, G. Dekanosidze,E. Kemertelidze, and E. Haslinger Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 8 . HCS-B 相似度:96.2% Chemistry of Natural Compounds 2004 40 561-564 ARJUNOLIC ACID DERIVATIVE GLYCOSIDE FROM THE STEMS OF Hedera colchica V. Mshvildadze, O. Kunert, G. DekanosidzeE. Kemertelidze,and E. Haslinger Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 9 . aglycone of J 相似度:96.2% Chemistry of Natural Compounds 2000 36 501-505 TRITERPENOID GLYCOSIDES OF Fatsia japonica.II. ISOLATION AND STRUCTURE OF GLYCOSIDES FROM THE LEAVES V. I. Grishkovets, E. A. Sobolev,A. S. Shashkov, and V. Ya. Chirva Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 10 . Tauroside St-G 1 相似度:96.2% Chemistry of Natural Compounds 1993 29 502-508 TRITERPENE GLYCOSIDES OF Hedera taurica.XI. STRUCTURES OF TAUROSIDES St-Gt, St-H1, and St-H FROM THE STEMS OF CRIMEAN IVY A. A. Shashkov, V. I. Grishkovets, O. Ya. Tsvetkov,and V. Ya. Chirva Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 11 . Tauroside G1 相似度:96.2% Chemistry of Natural Compounds 1992 28 455-460 TRITERPENE GLYCOSIDES OF HEDERA TAURICA IX. Structures of taurosides G1 G2 T3 H1,AND H2 FROM THE LEAVES OF CRIMEAN IVY V.I.GRISHKOVETS,N.V.TOLKACHEVA,A.S.SSHASHKOV,AND V.YA.CHIRVA Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 12 . 3-O-α-L- arabinopyranosyl-hederagenin-28-O-α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→6)-β-D- glucopyranosyl ester 相似度:96.2% Journal of Asian Natural Products Research 2007 9 175-182 Triterpenoid saponins from Stauntonia chinensis H. GAO, X. ZHANG, N.-L. WANG, H.-W. LIU, Q.-H. ZHANG,S.-S. SONG, Y. YU and X.-S. YAO Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 13 . 3-O-α-L-arabinopyranosyl-hederagenin 28-O-α-L-rhamnopyranosyl (1→4)-β-D-glucopyranosyl (1→6)-β-D-glucopyranosyl ester 相似度:96.2% Acta Pharmaceutica Sinica 2007 Vol 42 862-866 Triterpene glycosides from the aerial parts of Pulsatilla chinensis SHI Bao-jun; Li Qian; ZHANG Xiao-qi; WANG Ying; YE Wen-cai Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 14 . Cauloside D C53H86O22 相似度:96.2% Phytochemistry 1994 37 1131-1137 Oleanane and ursane glycosides from Schefflera octophylla Chizuko Maeda, Kazuhiro Ohtani, Ryoji Kasai, Kazuo Yamasaki, Nguyen Minh Duc, Nguyen Thoi Nham, Nguyen Khac Quynh Cu Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 15 . 3-O-(α-L-arabinopyranosyl)-Hederagenin-28-O-[α-L- rhumnopyranosyl(1→4)β-D-glucopyranosyl(1→6)-β-D-glucopyrunosyl] ester 相似度:96.2% Phytochemistry 1993 34 1389-1394 Triterpenoid glycosides from Stauntonia hexaphylla Huai-Bin Wang, Ralf Mayer, Gerhard Rücker Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 16 . hederaginin 3-O-α-L-arabinopyranoside(Cauloside D) 相似度:96.2% Chemical Journal of Chinese Universities 2001 22 1338-1341 The Chemical Constituents from Anemone Rivularis LIAO Xun, LIBo-Gang, WANG Ming-Kui, DING Li-Sheng Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 17 . cauloside D C53H86O22 相似度:96.2% Phytochemistry 1990 29 595-599 Triterpenoid saponins from Pulsatilla campanella Xing-Cong Li,De-Zu Wang,Su-Gong Wu,Chong-Ren Yang Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 18 . Kizuta saponin K C53H86O22 相似度:96.2% China Journal of Chinese Materia Medica 2014 39 4629-4636 Triterpenoids from Stauntonia obovatifoliola Hayata subsp. intermedia stems LU Xu-ran,LIU Shuo,WANG Man-yuan, GONG Mu-xin ,WANG Zhi-min, CHEN Xiao-qing Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 19 . cauloside D 相似度:96.2% Planta Medica 2013 78 673-679 Triterpenoid Saponins with Anti-Myocardial Ischemia Activity from the Whole Plants of Clematis tangutica Zhang, Wei; Yao, Min-Na; Tang, Hai-Feng; Tian, Xiang-Rong; Wang, Min-Chang; Ji, Lan-Ju; Xi, Miao-Miao: Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 20 . 3-O-α-L-rhamnopyranosyl-(1→2)-α-L-arabinopyranosyl-28-O-β-D-glucopyranosyl(1→6)-β-D-glucopyranoside hederagenin 相似度:96.2% Chinese Joumal of Experimental Traditional Medical Fomulae 2013 19 56-60 Chemical Constituents from Akebia trifoliata LI Zhi-feng, WANG Qi, LIU Yan-ting, LI Xiang, OUYANG Sheng, FENG Yu-lin, YANG Shi-lin Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 21 . Staunoside B C54H88O23 相似度:94.4% Helvetica Chimica Acta 2000 83 1454−1464 Tensioactive Compounds from the Aquatic Plant Ranunculus fluitans L. (Ranunculaceae) Christian Wegner, Matthias Hamburger, Olaf Kunert and Ernst Haslinger Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 22 . 3-O-α-L-arabinopyranosyl hederagenin 28-O-α-Z-rhamno-pyranosyl(1→4)-β-D-glucopyranosyl(1→6)-β-D-glucopyranosyl ester] 相似度:94.4% Chinese Traditional and Herbal Drugs 2008 39 819-822 興安白頭翁根莖的化學成分研究 孫輝;李茜;葉文才;趙守訓;姚新生 Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 23 . cauloside D C53H86O22 相似度:94.4% Journal of Agricultural and Food Chemistry 2001 49 5969-5974 Characterization of the Triterpene Saponins of the Roots and Rhizomes of Blue Cohosh (Caulophyllum Thalictroides) Jin-Woo Jhoo, Shengmin Sang, Kan He, Xiaofang Cheng, Nanqun Zhu, Ruth E. Stark, Qun Yi Zheng, Robert T. Rosen, and Chi-Tang Ho Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 24 . saponins HCS-B 相似度:94.4% Chinese Traditional and Herbal Drugs 2012 43 2141-2145 Study on glycosides from stems of Schefflera kwangsiensis ZHANG Qiao; SHEN Juan; ZHAO Yi-wu; WANG Zhen-zhong; XIAO Wei; Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 25 . compound 4 相似度:92.7% Chemistry of Natural Compounds 2005 41 194-199 TRITERPENE GLYCOSIDES FROM Kalopanax septemlobum.1. GLYCOSIDES A, B, C, F, G1, G2, I2, H, AND J FROM LEAVES OF Kalopanax septemlobum VAR. maximowichiiINTRODUCED TO CRIMEA V. I. Grishkovets, D. A. Panov,V. V. Kachala, and A. S. Shashkov Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 26 . compound 4 相似度:92.7% Chemistry of Natural Compounds 2005 41 436-441 TRITERPENE GLYCOSIDES FROM Cussonia paniculata.II. ACETYLATED GLYCOSIDES FROM LEAVES V. I. Grishkovets, I. I. Dovgii, V. V. Kachala,and A. S. Shashkov Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 27 . tanguticoside A C54H88O23 相似度:92.5% Planta Medica 2001 67 484-488 Triterpenoid Saponins from Clematis tangutica Hui Min Zhong, Chang Xiang Chen, Xuan Tian,Yu Xin Chui, Yao Zu Chen Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 28 . compound 5a 相似度:92.5% Chemistry of Natural Compounds 2005 41 436-441 TRITERPENE GLYCOSIDES FROM Cussonia paniculata.II. ACETYLATED GLYCOSIDES FROM LEAVES V. I. Grishkovets, I. I. Dovgii, V. V. Kachala,and A. S. Shashkov Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 29 . Tauroside St-H 1 相似度:92.5% Chemistry of Natural Compounds 1993 29 502-508 TRITERPENE GLYCOSIDES OF Hedera taurica.XI. STRUCTURES OF TAUROSIDES St-Gt, St-H1, and St-H FROM THE STEMS OF CRIMEAN IVY A. A. Shashkov, V. I. Grishkovets, O. Ya. Tsvetkov,and V. Ya. Chirva Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 30 . dipsacoside B C53H86O22 相似度:92.5% Acta Pharmaceutica Sinica 2000 Vol 35 756-759 TRITERPENE SAPONINS FROM PULSATILLA CERNUA ZHANG Qing-wen; YE Wen-cai; CHE Chun-tao; ZHAO Shou-xun Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 31 . staunoside B 相似度:92.5% Phytochemistry 1993 33 1469-1473 Triterpenoid glycosides from Stauntonia hexaphylla Huai-Bin Wang, Ralf Mayer, Gerhard Rücker Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 32 . cauloside D 相似度:92.5% Indian Journal of Chemistry Section B 2002 41B 677-680 A new nortriterpenoid saponin from Sinofranchetia chinensis Hemsl Xiaohui Yang, Ruijun Ma, Quan Xia, Runhua Lu, Xiaoning Wei, Hanqing Wang, Jie Kong Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 33 . tauroside St-H1 相似度:92.5% Chinese Traditional and Herbal Drugs 2012 43 2141-2145 Study on glycosides from stems of Schefflera kwangsiensis ZHANG Qiao; SHEN Juan; ZHAO Yi-wu; WANG Zhen-zhong; XIAO Wei; Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 34 . clematibetoside C 相似度:92.5% Planta Medica 2013 78 673-679 Triterpenoid Saponins with Anti-Myocardial Ischemia Activity from the Whole Plants of Clematis tangutica Zhang, Wei; Yao, Min-Na; Tang, Hai-Feng; Tian, Xiang-Rong; Wang, Min-Chang; Ji, Lan-Ju; Xi, Miao-Miao: Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 35 . loniceroside C 相似度:92.5% China Journal of Chinese Materia Medica 2011 36 1613-1619 Chemical constitutents from pre-formulation of Lonicerae Japonicae Flos in Shuanghuanglian lyophilized powder for injection WANG, Nan, YANG, Xiuwei Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 36 . 3-O-α-L-rhamnopyranosyl-(1→2)-O-α-L-arabinopyranoside-28-O-β-D-glucopyranosyl-(1→6)-O-β-D-glucopyranosyl ester of hederagenin 相似度:92.5% Chinese Joumal of Experimental Traditional Medical Fomulae 2011 17 92-96 Chemical Constituents from Kalopanax septemlobus FAN Yan-jun, CHENG Dong-yan, WANG Li-shu Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 37 . compound 5b 相似度:90.9% Chemistry of Natural Compounds 2005 41 436-441 TRITERPENE GLYCOSIDES FROM Cussonia paniculata.II. ACETYLATED GLYCOSIDES FROM LEAVES V. I. Grishkovets, I. I. Dovgii, V. V. Kachala,and A. S. Shashkov Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 38 . ST-K 相似度:90.9% Chemistry of Natural Compounds 1997 33 305-309 TRITERPENE GLYCOSIDES OF Hedera taurica XIV. STRUCTURES OF GLYCOSIDES St-Go_2, St-J, AND St-K FROM THE STEMS OF CRIMEAN IVY V. I. Grishkovets, O. Ya. Tsvetkov, A. S. Shashkov,and V. Ya. Chirva Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 39 . loniceroside C C53H86O22 相似度:90.7% Chemical & Pharmaceutical Bulletin 2003 51(3) 333-335 Loniceroside C, an Antiinflammatory Saponin from Lonicera japonica Wie Jong KWAK,Chang Kyun HAN, Hyeun Wook CHANG,Hyun Pyo KIM,Sam Sik KANG,and Kun Ho SON Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 40 . clematibetoside C C53H86O22 相似度:90.7% Chemical & Pharmaceutical Bulletin 2001 49(5) 635-638 Studies on the Constituents of Clematis Species. VIII. Triterpenoid Saponins from the Aerial Part of Clematis tibetana KUNTZ Yukio KAWATA, Haruhisa KIZU, Yukinori MIYAICHI, and Tsuyoshi TOMIMORI Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 41 . 3-O-α-L-rhamnopyranosyl(1→2)-α-L-arabinopyranosyl-hederagenin-28-O-β-D-glucopyranosyl(1→6)-β-D-glucopyranosyl ester C53H86O22 相似度:90.7% Acta Botanica Yunnanica 2000 22(2) 201-208 Triterpenoid Glycosides from the Lonicera japonica CHEN Chang-Xiang,WANGWei-Wei,NI Wei,CHEN Neng-Yu,ZHOU Jun Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 42 . thalictoside VI C53H86O22 相似度:90.7% Chemical & Pharmaceutical Bulletin 1994 42 101-104 Triterpene Glycosides from Thalictri Herba. II Hitoshi YOSHIMITU,Kazuhiro HAYASHI,Miki KUMABE and Toshihiro NOHARA Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 43 . glycoside pair G 相似度:90.7% Chemistry of Natural Compounds 2006 42 61-66 TRITERPENE GLYCOSIDES FROM Kalopanax septemlobum.VII. MINOR GLYCOSIDES FROM STEMS OF Kalopanax septemlobumVAR. maximowiczii AND Kalopanax septemlobum VAR. typicum D. A. Panov, V. I. Grishkovets, V. V. Kachala, and A. S. Shashkov Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 44 . L-G1 相似度:90.7% Chemistry of Natural Compounds 1999 35 543-546 TRITERPENE GLYCOSIDES FROM Hedera canariensis.VI. STRUCTURE OF L-G1, AND L-G1b GLYCOSIDES FROM LEAVES OF CANARY IVY L. A. Yakovishin, I V. I. Grishkovets, A. S. Shashkov, and V. Ya. Chirva Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 45 . tauroside G3 相似度:90.7% Chemistry of Natural Compounds 1992 28 455-460 TRITERPENE GLYCOSIDES OF HEDERA TAURICA IX. Structures of taurosides G1 G2 T3 H1,AND H2 FROM THE LEAVES OF CRIMEAN IVY V.I.GRISHKOVETS,N.V.TOLKACHEVA,A.S.SSHASHKOV,AND V.YA.CHIRVA Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 46 . tanguticoside A C54H88O23 相似度:90.7% Chinese Chemical Letters 1999 10 391-394 Triterpenoid Saponins from Clematis tangutica Hui Min ZHONG, Chang XianG CHEN:. Xuan TIAN, Yu Xin CHUI ,Yao Zu CHEN Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 47 . 3-O-[β-D-xylopyranosyl-(1→3)-α-L-rhamnopyranosyl-(1→2)-α-L-arabinpyranosyl]-28-O-β-D-glucopyranosyl-hederagenin 相似度:90.7% Journal of Shenyang Pharmaceutical University 2007 24 215-218 Chemical constituents of Nigella glandulifera Freyn NI Jun-jun, WU Zhao-hua, GAO Hui-yuan, WANG Zhe-xing, WU Li-jun Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 48 . leonticin D C53H86O23 相似度:90.7% Journal of Agricultural and Food Chemistry 2001 49 5969-5974 Characterization of the Triterpene Saponins of the Roots and Rhizomes of Blue Cohosh (Caulophyllum Thalictroides) Jin-Woo Jhoo, Shengmin Sang, Kan He, Xiaofang Cheng, Nanqun Zhu, Ruth E. Stark, Qun Yi Zheng, Robert T. Rosen, and Chi-Tang Ho Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 49 . loniceroside A 相似度:90.7% China Journal of Chinese Materia Medica 2011 36 1613-1619 Chemical constitutents from pre-formulation of Lonicerae Japonicae Flos in Shuanghuanglian lyophilized powder for injection WANG, Nan, YANG, Xiuwei Structure 13C NMR 碳譜模擬圖 -------------------------------------------------------------------------------- 50 . 3-O-[β-D-glucopyranosyl-(1→3)-α-L-arabinopyranosyl]-28-O-[α-L-rhamnopyranosyl-(1→4)-β-D-glucopyranosyl-(1→6)-β-D-glucopyranosyl]hederagenin C59H96O27 相似度:89.8% Helvetica Chimica Acta 2000 83 1454−1464 Tensioactive Compounds from the Aquatic Plant Ranunculus fluitans L. (Ranunculaceae) Christian Wegner, Matthias Hamburger, Olaf Kunert and Ernst Haslinger Structure 13C NMR 碳譜模擬圖 |
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[考研] 318求調劑 +3 | 篤行致遠. 2026-03-31 | 3/150 |
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[考研] 求調劑 +9 | akdhjs 2026-03-31 | 10/500 |
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[考研] 287求調劑 +17 | land xuxu 2026-03-26 | 17/850 |
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[考研] 085701環(huán)境工程求調劑 +11 | 多久上課 2026-03-27 | 12/600 |
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[考研]
 304材料求調劑
+5
|
鐘llll 2026-03-26 | 5/250 |
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[考研] 085600 286分 材料求調劑 +11 | 麻辣魷魚 2026-03-27 | 12/600 |
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[考研] 329求調劑 +8 | 星野? 2026-03-26 | 8/400 |
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[考研] 一志愿北京工業(yè)大學，324分求調劑 +6 | 零八# 2026-03-28 | 6/300 |
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[考研] 295求調劑 +5 | 1428151015 2026-03-27 | 6/300 |
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[考研] 315調劑 +4 | 0860求調劑 2026-03-26 | 5/250 |
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[考研] 打過很多競賽，085406控制工程300分，求調劑 +3 | askeladz 2026-03-26 | 3/150 |
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