 |
 |
 |
 |
 |
 |
||
 |
 |
 |
 |
 |
| 5 | 1/1 | 返回列表 |
| 查看: 1239 | 回復(fù): 4 | ||
| 本帖產(chǎn)生 1 個(gè) 翻譯EPI ，點(diǎn)擊這里進(jìn)行查看 | ||
白玉浴血木蟲 (正式寫手)
|
[求助]
請(qǐng)問(wèn)這里的百分?jǐn)?shù)都表示的是什么呢？
|
|
|
For comprehending the solvation dynamics process, a thorough understanding of the micellar structure and location of the probe within the micelle is necessary. The dielectric constant is an important tool for measuring the polarity of a solvent, which changes from bulk solvent to micellar solution with the probe in the palisade layer.72 According to the molecular approach for the solvation relaxation process, which takes into account the solvent structures around the probe, it appears to be more logical to understand the results in micellar media, although it is more complicated than the homogeneous solution. Inside the micellar palisade layer, the movement of the water molecules is much more hindered than the bulk water molecules, hence it is expected that the solvation process inside the micelle should be slower than that in the bulk. The water molecules adjacent to the probe are much more restricted and difficult to rearrange than the water molecules somewhat away from the probe. So the slower solvation component arises from the response of the few restricted water molecules that are adjacent to the probe, and the collective response of the relatively large number of water molecules that are not in the vicinity of the probe gives rise to the faster solvation component.75 From UV−visible spectra, fluorescence spectra, and also anisotropy values, one can conclude that the probe molecules reside inside the palisade layer of the micelles. The average solvation time of C- 343 at 298 K in aqueous solution of 28 mM SB-16 was found to be 2.02 ns (Table 3), with components 0.64 ns (80%) and 7.57 ns (20%). The process becomes faster in the presence of both the surfactant (SDS) and the RTIL (EmimOs), and the effect is more pronounced in the case of SDS. With the addition of 10 mM EmimOs and SDS to 28 mM SB-16 solution, the average solvation time changes from 2.02 to 1.36 and 1.00 ns, respectively. The slow component of the solvation time of C- 343 at 298 K in 28 mM SB-16 solution was found to be 7.57 ns with amplitude of 20%. With addition of 10 mM EmimOs, this value decreases from 7.57 to 3.23 ns and the amplitude changes from 20% to 33%, which clearly indicates that the strength of the hydrogen bonding decreases but the water penetration increases. On addition of 10 mM SDS to the 28 mM SB-16 solution, the slow component decreases from 7.57 to 1.19 ns and the amplitude increases from 20% to 76% which suggests that the strength of hydrogen bonding decreases while the water penetration increases abnormally. This is a manifestation of the movement of the probe molecules to the bulk water phase. |
回復(fù)此樓» 猜你喜歡
265求調(diào)劑
已經(jīng)有4人回復(fù)
-
085700資源與環(huán)境308求調(diào)劑
已經(jīng)有6人回復(fù)
-
一志愿吉林大學(xué)材料學(xué)碩321求調(diào)劑
已經(jīng)有12人回復(fù)
-
286分人工智能專業(yè)請(qǐng)求調(diào)劑愿意跨考！
已經(jīng)有3人回復(fù)
-
329求調(diào)劑
已經(jīng)有5人回復(fù)
-
申請(qǐng)回稿延期一個(gè)月，編輯同意了。但系統(tǒng)上的時(shí)間沒(méi)變，給編輯又寫郵件了，沒(méi)回復(fù)
已經(jīng)有4人回復(fù)
-
材料學(xué)碩318求調(diào)劑
已經(jīng)有5人回復(fù)
-
一志愿中國(guó)海洋大學(xué)，生物學(xué)，301分，求調(diào)劑
已經(jīng)有6人回復(fù)
-
081700化工學(xué)碩調(diào)劑
已經(jīng)有3人回復(fù)
-
一志愿蘇州大學(xué)材料求調(diào)劑，總分315（英一）
已經(jīng)有3人回復(fù)
baoshanqiu
至尊木蟲 (著名寫手)
- 翻譯EPI: 204
- 應(yīng)助: 103 (高中生)
- 金幣: 15293.5
- 紅花: 41
- 帖子: 1611
- 在線: 431.6小時(shí)
- 蟲號(hào): 3856202
- 注冊(cè): 2015-05-08
- 性別: GG
- 專業(yè): 胃腸道免疫相關(guān)疾病
【答案】應(yīng)助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★
白玉浴血: 金幣+5, 翻譯EPI+1, ★有幫助 2015-08-29 08:32:35
白玉浴血(RXMCDM代發(fā)): 金幣+5 2015-09-02 23:10:07
白玉浴血: 金幣+5, 翻譯EPI+1, ★有幫助 2015-08-29 08:32:35
白玉浴血(RXMCDM代發(fā)): 金幣+5 2015-09-02 23:10:07
|
The average solvation time of C-343 at 298 K in aqueous solution of 28 mM SB-16 was found to be 2.02 ns (Table 3), with components 0.64 ns (80%) and 7.57ns (20%). 這里可能是不同組分的溶劑化時(shí)間分布，有80%為0.64 ns，20%為7.57ns，平均0.64x80%+7.57x20%=2.02ns. 這些百分比看來(lái)是該類組分的豐度（含量百分比）。 The slow component of the solvation time of C-343 at 298 K in 28 mM SB-16 solution was found to be 7.57 ns with amplitude of 20% 慢組分的溶劑化時(shí)間 7.57 ns豐度20% With addition of 10 mM EmimOs, this value decreases from 7.57 to 3.23 ns and the amplitude changes from 20% to 33%, 加EmimOs后該值（溶劑化時(shí)間）變?yōu)?.23 ns，豐度由20% 變?yōu)?33%。 余同。 |
2樓2015-08-28 21:50:55
白玉浴血
木蟲 (正式寫手)
- 應(yīng)助: 0 (幼兒園)
- 金幣: 2513.6
- 散金: 102
- 紅花: 8
- 帖子: 838
- 在線: 243.2小時(shí)
- 蟲號(hào): 2684358
- 注冊(cè): 2013-09-27
- 性別: MM
- 專業(yè): 高分子組裝與超分子結(jié)構(gòu)
3樓2015-08-29 08:33:28
baoshanqiu
至尊木蟲 (著名寫手)
- 翻譯EPI: 204
- 應(yīng)助: 103 (高中生)
- 金幣: 15293.5
- 紅花: 41
- 帖子: 1611
- 在線: 431.6小時(shí)
- 蟲號(hào): 3856202
- 注冊(cè): 2015-05-08
- 性別: GG
- 專業(yè): 胃腸道免疫相關(guān)疾病
4樓2015-08-30 08:33:57
白玉浴血
木蟲 (正式寫手)
- 應(yīng)助: 0 (幼兒園)
- 金幣: 2513.6
- 散金: 102
- 紅花: 8
- 帖子: 838
- 在線: 243.2小時(shí)
- 蟲號(hào): 2684358
- 注冊(cè): 2013-09-27
- 性別: MM
- 專業(yè): 高分子組裝與超分子結(jié)構(gòu)
5樓2015-08-31 08:11:19
相關(guān)版塊跳轉(zhuǎn)
我要訂閱樓主 白玉浴血 的主題更新
| 5 | 1/1 | 返回列表 |
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 085700資源與環(huán)境308求調(diào)劑 +6 | 墨墨漠 2026-03-18 | 6/300 |
|
|---|---|---|---|---|
|
|
[考研] 307求調(diào)劑 +9 | 冷笙123 2026-03-17 | 9/450 |
|
|
|
[考研] 288求調(diào)劑，一志愿華南理工大學(xué)071005 +5 | ioodiiij 2026-03-17 | 5/250 |
|
|
[考研] 317求調(diào)劑 +3 | 申子申申 2026-03-19 | 6/300 |
|
|
|
[考研] 求調(diào)劑 +3 | Mqqqqqq 2026-03-19 | 3/150 |
|
|
|
[考研] 085600材料與化工求調(diào)劑 +6 | 緒幸與子 2026-03-17 | 6/300 |
|
|
|
[考研] 一志愿985，本科211，0817化學(xué)工程與技術(shù)319求調(diào)劑 +10 | Liwangman 2026-03-15 | 10/500 |
|
|
|
[考研] 295求調(diào)劑 +3 | 一志愿京區(qū)211 2026-03-18 | 5/250 |
|
|
|
[考研] 299求調(diào)劑 +5 | △小透明* 2026-03-17 | 5/250 |
|
|
|
[考研] 材料，紡織，生物（0856、0710），化學(xué)招生啦 +3 | Eember. 2026-03-17 | 9/450 |
|
|
|
[考研] 268求調(diào)劑 +6 | 簡(jiǎn)單點(diǎn)0 2026-03-17 | 6/300 |
|
|
|
[考研] 278求調(diào)劑 +5 | 煙火先于春 2026-03-17 | 5/250 |
|
|
|
[基金申請(qǐng)] 被我言中：新模板不強(qiáng)調(diào)格式了，假專家開始管格式了 +4 | beefly 2026-03-14 | 4/200 |
|
|
|
[考研] 材料與化工專碩調(diào)劑 +5 | heming3743 2026-03-16 | 5/250 |
|
|
|
[論文投稿] 有沒(méi)有大佬發(fā)小論文能帶我個(gè)二作 +3 | 增銳漏人 2026-03-17 | 4/200 |
|
|
|
[考研] 東南大學(xué)364求調(diào)劑 +5 | JasonYuiui 2026-03-15 | 5/250 |
|
|
|
[考研] 0854控制工程 359求調(diào)劑 可跨專業(yè) +3 | 626776879 2026-03-14 | 9/450 |
|
|
|
[考研] 一志愿211 0703方向310分求調(diào)劑 +3 | 努力奮斗112 2026-03-15 | 3/150 |
|
|
|
[考研] 0703化學(xué)調(diào)劑 290分有科研經(jīng)歷，論文在投 +7 | 膩膩gk 2026-03-14 | 7/350 |
|
|
|
[考研] 297一志愿上交085600求調(diào)劑 +5 | 指尖八千里 2026-03-14 | 5/250 |
|