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Improved mechanical property, thermal performance, flame retardancy and fire behavior of lignin-based rigid polyurethane foam nanocomposite 作者:Gao, LP (Gao, Liping)[ 1 ] ; Zheng, GY (Zheng, Guangyao)[ 1 ] ; Zhou, YH (Zhou, Yonghong)[ 1 ] ; Hu, LH (Hu, Lihong)[ 1 ] ; Feng, GD (Feng, Guodong)[ 1 ] JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 卷: 120 期: 2 頁: 1311-1325 DOI: 10.1007/s10973-015-4434-2 出版年: MAY 2015 查看期刊信息 摘要 Liquefied lignin-based polyol (LBP) was successfully obtained by liquefying calcium lignosulphonate with a polyhydroxy alcohol mixture, which can substitute 30 % petroleum-based polyether polyol to prepare rigid polyurethane foam (RPUF). In an effort to reduce the flammability and smoke release from RPUF, liquefied LBP in combination with commercial flame retardant polyol (FRP), polyurethane microencapsulated ammonium polyphosphate (MAPP) and organically modified layered double hydroxide (OLDH) were used to fabricate halogen-free flame retardant RPUF nanocomposite. The influences of incorporating LBP, FRP, MAPP and OLDH into RPUF on the thermal conductivity, mechanical property, thermal performance, flame retardancy and fire behaviors of RPUFs were comprehensively investigated. It is noteworthy that simultaneously incorporating LBP, FRP, MAPP and OLDH into RPUF can significantly improve the mechanical property, thermal performance, flame retardancy and fire behavior of RPUF. The improved flame retardancy and fire behavior of RPUF are attributable to combined effects among LBP, FRP, MAPP and OLDH in gas phase and condensed phase. 關(guān)鍵詞 作者關(guān)鍵詞:Mechanical property; Thermal performance; Flame retardancy; Fire behavior; Rigid polyurethane foam nanocomposite KeyWords Plus:LAYERED DOUBLE HYDROXIDE; POLYMERS; POLYOLS; OXYPROPYLATION; COMBUSTION; CHEMISTRY 作者信息 通訊作者地址: Zheng, GY (通訊作者) Inst Chem Ind Forest Prod, Natl Engn & Technol Res Ctr Forest Chem Ind, Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China. 地址: [ 1 ] Inst Chem Ind Forest Prod, Natl Engn & Technol Res Ctr Forest Chem Ind, Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China 電子郵件地址:zhguya@sina.com 基金資助致謝 基金資助機構(gòu) 授權(quán)號 Jiangsu Province Natural Science Foundation of China BK20130071 National 12th Five-year Science and Technology Support Plan 2012BAD32B05 查看基金資助信息 出版商 SPRINGER, VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS 類別 / 分類 研究方向:Chemistry Web of Science 類別:Chemistry, Analytical; Chemistry, Physical 文獻信息 文獻類型:Article 語種:English 入藏號: WOS:000352480800027 ISSN: 1388-6150 eISSN: 1572-8943 期刊信息 目錄： Current Contents Connect® Impact Factor (影響因子): Journal Citation Reports® 其他信息 IDS 號: CF3WX Web of Science 核心合集中的 "引用的參考文獻": 29 Web of Science 核心合集中的 "被引頻次": 0 |
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Improved mechanical property, thermal performance, flame retardancy and fire behavior of lignin-based rigid polyurethane foam nanocomposite 作者:Gao, LP (Gao, Liping)[ 1 ] ; Zheng, GY (Zheng, Guangyao)[ 1 ] ; Zhou, YH (Zhou, Yonghong)[ 1 ] ; Hu, LH (Hu, Lihong)[ 1 ] ; Feng, GD (Feng, Guodong)[ 1 ] JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY 卷: 120 期: 2 頁: 1311-1325 DOI: 10.1007/s10973-015-4434-2 出版年: MAY 2015 查看期刊信息 摘要 Liquefied lignin-based polyol (LBP) was successfully obtained by liquefying calcium lignosulphonate with a polyhydroxy alcohol mixture, which can substitute 30 % petroleum-based polyether polyol to prepare rigid polyurethane foam (RPUF). In an effort to reduce the flammability and smoke release from RPUF, liquefied LBP in combination with commercial flame retardant polyol (FRP), polyurethane microencapsulated ammonium polyphosphate (MAPP) and organically modified layered double hydroxide (OLDH) were used to fabricate halogen-free flame retardant RPUF nanocomposite. The influences of incorporating LBP, FRP, MAPP and OLDH into RPUF on the thermal conductivity, mechanical property, thermal performance, flame retardancy and fire behaviors of RPUFs were comprehensively investigated. It is noteworthy that simultaneously incorporating LBP, FRP, MAPP and OLDH into RPUF can significantly improve the mechanical property, thermal performance, flame retardancy and fire behavior of RPUF. The improved flame retardancy and fire behavior of RPUF are attributable to combined effects among LBP, FRP, MAPP and OLDH in gas phase and condensed phase. 關(guān)鍵詞 作者關(guān)鍵詞:Mechanical property; Thermal performance; Flame retardancy; Fire behavior; Rigid polyurethane foam nanocomposite KeyWords Plus:LAYERED DOUBLE HYDROXIDE; POLYMERS; POLYOLS; OXYPROPYLATION; COMBUSTION; CHEMISTRY 作者信息 通訊作者地址: Zheng, GY (通訊作者) Inst Chem Ind Forest Prod, Natl Engn & Technol Res Ctr Forest Chem Ind, Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China. 地址: [ 1 ] Inst Chem Ind Forest Prod, Natl Engn & Technol Res Ctr Forest Chem Ind, Key Lab Biomass Energy & Mat, Nanjing 210042, Jiangsu, Peoples R China 電子郵件地址:zhguya@sina.com 基金資助致謝 基金資助機構(gòu) 授權(quán)號 Jiangsu Province Natural Science Foundation of China BK20130071 National 12th Five-year Science and Technology Support Plan 2012BAD32B05 查看基金資助信息 出版商 SPRINGER, VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS 類別 / 分類 研究方向:Chemistry Web of Science 類別:Chemistry, Analytical; Chemistry, Physical 文獻信息 文獻類型:Article 語種:English 入藏號: WOS:000352480800027 ISSN: 1388-6150 eISSN: 1572-8943 期刊信息 目錄： Current Contents Connect® Impact Factor (影響因子): Journal Citation Reports® 其他信息 IDS 號: CF3WX Web of Science 核心合集中的 "引用的參考文獻": 29 Web of Science 核心合集中的 "被引頻次": 0 |
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