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jimmywhite419銀蟲 (小有名氣)
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Nature com.上新出的鋰硫電池文章,跟大家討論分享一下 已有8人參與
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Nature com.上新出的鋰硫電池文章,跟大家討論分享一下:![]() http://www.nature.com/ncomms/201 ... ull/ncomms9622.html Encapsulation of sulfur with thin-layered nickel-based hydroxides for long-cyclic lithium–sulfur cells Abstract:Elemental sulfur cathodes for lithium/sulfur cells are still in the stage of intensive research due to their unsatisfactory capacity retention and cyclability. The undesired capacity degradation upon cycling originates from gradual diffusion of lithium polysulfides out of the cathode region. To prevent losses of certain intermediate soluble species and extend lifespan of cells, the effective encapsulation of sulfur plays a critical role. Here we report an applicable way, by using thin-layered nickel-based hydroxide as a feasible and effective encapsulation material. In addition to being a durable physical barrier, such hydroxide thin films can irreversibly react with lithium to generate protective layers that combine good ionic permeability and abundant functional polar/hydrophilic groups, leading to drastic improvements in cell behaviours (almost 100% coulombic efficiency and negligible capacity decay within total 500 cycles). Our present encapsulation strategy and understanding of hydroxide working mechanisms may advance progress on the development of lithium/sulfur cells for practical use. QQ圖片20151017104712.png |
納米技術(shù)與能源及模擬 | Nature Science Cell |
銅蟲 (職業(yè)作家)
金蟲 (著名寫手)
電之煉金術(shù)士
木蟲 (著名寫手)
銀蟲 (小有名氣)
銀蟲 (小有名氣)
銀蟲 (小有名氣)
銀蟲 (小有名氣)
銀蟲 (小有名氣)
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