版塊導(dǎo)航: 正在加載中...

應(yīng)《網(wǎng)絡(luò)安全法》要求，自2017年10月1日起，未進(jìn)行實(shí)名認(rèn)證將不得使用互聯(lián)網(wǎng)跟帖服務(wù)。為保障您的帳號(hào)能夠正常使用，請(qǐng)盡快對(duì)帳號(hào)進(jìn)行手機(jī)號(hào)驗(yàn)證，感謝您的理解與支持！

24小時(shí)熱門版塊排行榜

返回列表

zhaojing5022

新蟲 (小有名氣)

應(yīng)助: 0 (幼兒園)
金幣: 1419.8
散金: 5
帖子: 97
在線: 31.2小時(shí)
蟲號(hào): 2735989
注冊(cè): 2013-10-19
性別: MM
專業(yè): 計(jì)算數(shù)學(xué)與科學(xué)工程計(jì)算

[求助] 這是審稿人提的問(wèn)題，沒理解要讓干什么，求翻譯已有1人參與

Question 3: The reference potential for the CVs (Fig. 6) should be indicated, either on the axis label and/or in the figure caption.
Question 4: For the insets in Fig. 6, the best-fit lines should be shown, as opposed to just connecting the successive data points.
Question 5: I fail to see how the redox process is diffusion controlled for these compounds. The complexes are insoluble and immobilized on the graphite working electrode, so there shouldn’t be any diffusion of the electroactive species. The peak current should then scale linearly with the scan rate, as is typically observed for immobilized species. The authors should revisit this data and reconsider their conclusion before publishing. If they are confident in their conclusion of a diffusion-limited process, I would appreciate some reasonable chemical explanation for why the current is diffusion controlled.
Question 6: It is unclear what conclusions are to be drawn from the cyclic voltammetry. In general the authors do a better job of describing the results than contextualizing them, but particularly for the CVs the data is presented but not explained, and no chemical insights are provided.

回復(fù)此樓

» 猜你喜歡

306求0703調(diào)劑一志愿華中師范已經(jīng)有9人回復(fù)
一志愿吉大化學(xué)322求調(diào)劑已經(jīng)有6人回復(fù)
求調(diào)劑已經(jīng)有5人回復(fù)
344求調(diào)劑已經(jīng)有3人回復(fù)
一志愿哈工大，085400，320，求調(diào)劑已經(jīng)有3人回復(fù)
【考研調(diào)劑】化學(xué)專業(yè) 281分，一志愿四川大學(xué)，誠(chéng)心求調(diào)劑已經(jīng)有13人回復(fù)
307求調(diào)劑已經(jīng)有3人回復(fù)
【雙一流院校新能源、環(huán)境材料，材料加工與模擬招收大量調(diào)劑】已經(jīng)有6人回復(fù)
26申博自薦已經(jīng)有3人回復(fù)
資源與環(huán)境調(diào)劑申請(qǐng)(333分) 已經(jīng)有6人回復(fù)

考研求助

1樓 2016-10-24 20:47:56

已閱回復(fù)此樓關(guān)注TA 給TA發(fā)消息送TA紅花 TA的回帖

erne8t

金蟲 (初入文壇)

應(yīng)助: 6 (幼兒園)
金幣: 649.8
紅花: 1
帖子: 40
在線: 58.3小時(shí)
蟲號(hào): 4022908
注冊(cè): 2015-08-15
性別: GG
專業(yè): 環(huán)境化工

【答案】應(yīng)助回帖

★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
感謝參與，應(yīng)助指數(shù) +1
zhaojing5022: 金幣+20, ★★★★★最佳答案 2016-10-25 15:39:08

問(wèn)題3：循環(huán)伏安圖（圖6）中應(yīng)當(dāng)在軸上或標(biāo)題注釋里標(biāo)上參考電位。
問(wèn)題4：圖6的插圖中不該僅僅把數(shù)據(jù)點(diǎn)順連，而應(yīng)當(dāng)給出最佳擬合線。
問(wèn)題5：我無(wú)法認(rèn)同這些化合物的氧化還原反應(yīng)是由擴(kuò)散控制的。這些復(fù)合物不溶于液體而附著在石墨工作電極上，所以不應(yīng)該存在電活性物質(zhì)的擴(kuò)散。與一般此類不可移動(dòng)附著物的情況相仿，峰值電流應(yīng)與掃描速率成線性正比。作者們應(yīng)該重新審視數(shù)據(jù)并重新斟酌結(jié)論。若是作者們對(duì)擴(kuò)散限制過(guò)程這個(gè)結(jié)論有信心，那么我會(huì)期待讀到關(guān)于為什么電流是擴(kuò)散控制的的合理化學(xué)解釋。
問(wèn)題6：從循環(huán)伏安圖中得出的結(jié)論沒有清晰地表達(dá)出來(lái)。一般來(lái)講，文獻(xiàn)作者會(huì)更好的描述結(jié)果而不是放在上下文中（讓讀者自行理解），尤其是針對(duì)循環(huán)伏安圖的只放結(jié)果而不給出化學(xué)反應(yīng)的見解。

贊一下(1人)

回復(fù)此樓

2樓2016-10-25 00:35:01

已閱回復(fù)此樓關(guān)注TA 給TA發(fā)消息送TA紅花 TA的回帖

相關(guān)版塊跳轉(zhuǎn) 我要訂閱樓主 zhaojing5022 的主題更新