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zhaojing5022新蟲 (小有名氣)
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[求助]
這是審稿人提的問題，沒理解要讓干什么，求翻譯 已有1人參與
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Question 3: The reference potential for the CVs (Fig. 6) should be indicated, either on the axis label and/or in the figure caption. Question 4: For the insets in Fig. 6, the best-fit lines should be shown, as opposed to just connecting the successive data points. Question 5: I fail to see how the redox process is diffusion controlled for these compounds. The complexes are insoluble and immobilized on the graphite working electrode, so there shouldn’t be any diffusion of the electroactive species. The peak current should then scale linearly with the scan rate, as is typically observed for immobilized species. The authors should revisit this data and reconsider their conclusion before publishing. If they are confident in their conclusion of a diffusion-limited process, I would appreciate some reasonable chemical explanation for why the current is diffusion controlled. Question 6: It is unclear what conclusions are to be drawn from the cyclic voltammetry. In general the authors do a better job of describing the results than contextualizing them, but particularly for the CVs the data is presented but not explained, and no chemical insights are provided. |
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【答案】應(yīng)助回帖
★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
感謝參與，應(yīng)助指數(shù) +1
zhaojing5022: 金幣+20, ★★★★★最佳答案 2016-10-25 15:39:08
感謝參與，應(yīng)助指數(shù) +1
zhaojing5022: 金幣+20, ★★★★★最佳答案 2016-10-25 15:39:08
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問題3：循環(huán)伏安圖（圖6）中應(yīng)當(dāng)在軸上或標(biāo)題注釋里標(biāo)上參考電位。 問題4：圖6的插圖中不該僅僅把數(shù)據(jù)點順連，而應(yīng)當(dāng)給出最佳擬合線。 問題5：我無法認(rèn)同這些化合物的氧化還原反應(yīng)是由擴(kuò)散控制的。這些復(fù)合物不溶于液體而附著在石墨工作電極上，所以不應(yīng)該存在電活性物質(zhì)的擴(kuò)散。與一般此類不可移動附著物的情況相仿，峰值電流應(yīng)與掃描速率成線性正比。作者們應(yīng)該重新審視數(shù)據(jù)并重新斟酌結(jié)論。若是作者們對擴(kuò)散限制過程這個結(jié)論有信心，那么我會期待讀到關(guān)于為什么電流是擴(kuò)散控制的的合理化學(xué)解釋。 問題6：從循環(huán)伏安圖中得出的結(jié)論沒有清晰地表達(dá)出來。一般來講，文獻(xiàn)作者會更好的描述結(jié)果而不是放在上下文中（讓讀者自行理解），尤其是針對循環(huán)伏安圖的只放結(jié)果而不給出化學(xué)反應(yīng)的見解。 |
2樓2016-10-25 00:35:01
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