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zhsj1112銅蟲 (小有名氣)
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[求助]
birnessite晶體解析!
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最近投了一篇稿子,這已經(jīng)是第三輪大修了。詳細(xì)審稿意見如下。 (2) Structure birnessites. I appreciate a thorough literature review on the crystallography of the birnessite. However, the structure and composition of birnessite strongly depends on the synthesis conditions, especially in case of the substrate-directed growth presented in this manuscript. Therefore, it absolutely necessary to perform structure refinement in this case. The explanation provided by the Authors can be true, but if not supported by experimental refinement cannot be accepted. Without the experimental structure refinement, the Authors need to remove their strong statements related to the positions ofMn(III) and ions between the layers. This however will also impact the conclusions made by the Authors. 本人做了一個beta-MnO2上面生長birnessite的復(fù)合物。因為進行了試驗條件的調(diào)控,birnessite里面的Mn3+含量有所提高。第二輪審稿意見追問提高的Mn3+在什么位置。所以查找相關(guān)文獻加以說明!可是審稿人并不信服,要求做structure refinement!本人在這方面完全沒有接觸過,看了一些資料,完全超出能夠理解的范圍,現(xiàn)求助: (1)可否在beta-MnO2上面生長birnessite的復(fù)合物做structure refinement?beta-MnO2和birnessite都已確定為單晶 (2)如果可以做,我需要采集哪些數(shù)據(jù)。確認(rèn)birnessite里面Mn3+和Mn4+的位置 (3)求助幫忙做structure refinement大神,金幣不多。其他方式答謝亦可! 這段時間急死了,吃不好,睡不著。希望能得到大神的幫助! |
金蟲 (小有名氣)

銅蟲 (小有名氣)
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