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【轉(zhuǎn)帖】MS中原子對前線軌道貢獻(xiàn)的計(jì)算實(shí)例 已有17人參與
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MS作量子化學(xué)計(jì)算,和GS一樣,可以計(jì)算所有原子的軌道系數(shù) 因?yàn)橐玫骄庉嬢斎胛募,使用關(guān)鍵字,所以好多人不知道 在你的輸入文件里任意一行加入 print eigenvectors 然后就可以在輸出文件里,就可以看到 all the MO coefficients To do this you need first to "save files" from the DMol3 or Castep calculation dialog, then edit the input file and finally use "run files." 看看這些軌道系數(shù),找到你的HOMO和LUMO,就知道每一個(gè)原子對前線軌道的貢獻(xiàn)了 對Castep只適合計(jì)算分子,不適合計(jì)算晶體。因?yàn)榫w的計(jì)算是固體物理的能帶理論。 舉一個(gè)簡單例子: 比如利用Dmol計(jì)算水分子,想看一看每個(gè)原子對前線對前線軌道計(jì)算 1、建立水分子模型 2、打開Dmol計(jì)算對話框,設(shè)置計(jì)算,你要計(jì)算的那些性能都選上 3、點(diǎn)擊Run運(yùn)行,這是就會(huì)產(chǎn)生一個(gè)input文件,然后停止運(yùn)行即可 4、打開input文件,在里面# Print options這一行下面(實(shí)際上任意一行都可以)寫上print eigenvectors,然后保存文件 5、讓input文件至于當(dāng)前對話框,打開Dmol計(jì)算對話框,點(diǎn)擊Files,然后Run File 6、查看你的outmol文件,里面就有所有原子的軌道組合系數(shù),你就可以看出每個(gè)原子對分子軌道的貢獻(xiàn)。找到你的HOMO、LUMO,就可以看出你的每個(gè)原子對前線軌道的貢獻(xiàn)。 對Dmol3分子軌道計(jì)算做點(diǎn)補(bǔ)充說明,最近中國科學(xué)B化學(xué)刊登了一篇關(guān)于PbCNN結(jié)構(gòu)的文章,改論文通過QM計(jì)算表明在Pb-C之間存在triple bond。我們以這個(gè)例子為研究對象,采用Dmol3這個(gè)功能進(jìn)行了計(jì)算,泛函采用BLYP形式,波函數(shù)機(jī)組采用DNP,即Double numerical basis+plarized basis,數(shù)值計(jì)算精度為fine。計(jì)算過程為了反應(yīng)波函數(shù)具體組合分成,輸入print eigenvectors 關(guān)鍵詞 最后得到如下計(jì)算結(jié)果: Symmetry group of the molecule: c*v Carbon nbas= 1, z= 6, nrfn= 7, rcut= 9.45, e_ref= -0.042518 Ha rcore= 0.00 zval= 6.00 6.00 n=1 L=0 occ= 2.00 e= -10.059732Ha -273.7394eV n=2 L=0 occ= 2.00 e= -0.497867Ha -13.5477eV n=2 L=1 occ= 2.00 e= -0.190572Ha -5.1857eV n=2 L=0 occ= 0.00 e= -1.480347Ha -40.2823eV n=2 L=1 occ= 0.00 e= -1.169346Ha -31.8195eV n=3 L=2 occ= 0.00 e= -2.722222Ha -74.0755eV n=3 L=2 occ= 0.00 e= -1.388876Ha -37.7932eV eliminated Nitrogen nbas= 2, z= 7, nrfn= 7, rcut= 9.45, e_ref= -0.107073 Ha rcore= 0.00 zval= 7.00 7.00 n=1 L=0 occ= 2.00 e= -14.152027Ha -385.0964eV n=2 L=0 occ= 2.00 e= -0.676218Ha -18.4008eV n=2 L=1 occ= 3.00 e= -0.258966Ha -7.0468eV n=2 L=0 occ= 0.00 e= -1.801528Ha -49.0221eV n=2 L=1 occ= 0.00 e= -1.380332Ha -37.5608eV n=3 L=2 occ= 0.00 e= -2.722222Ha -74.0755eV n=3 L=2 occ= 0.00 e= -1.388876Ha -37.7932eV eliminated Lead nbas= 3, z= 82, nrfn= 18, rcut= 9.45, e_ref= -0.022553 Ha rcore= 0.00 zval= 82.00 82.00 n=1 L=0 occ= 2.00 e= -2903.263585Ha -79001.8554eV n=2 L=0 occ= 2.00 e= -489.120791Ha -13309.6596eV n=2 L=1 occ= 6.00 e= -471.031618Ha -12817.4279eV n=3 L=0 occ= 2.00 e= -116.566037Ha -3171.9246eV n=3 L=1 occ= 6.00 e= -107.955115Ha -2937.6094eV n=3 L=2 occ=10.00 e= -91.875290Ha -2500.0549eV n=4 L=0 occ= 2.00 e= -25.764798Ha -701.0961eV n=4 L=1 occ= 6.00 e= -21.985690Ha -598.2613eV n=4 L=2 occ=10.00 e= -15.007279Ha -408.3690eV n=4 L=3 occ=14.00 e= -5.554004Ha -151.1322eV n=5 L=0 occ= 2.00 e= -4.180772Ha -113.7646eV n=5 L=1 occ= 6.00 e= -2.914053Ha -79.2954eV n=5 L=2 occ=10.00 e= -0.874176Ha -23.7876eV n=6 L=0 occ= 2.00 e= -0.331833Ha -9.0296eV n=6 L=1 occ= 2.00 e= -0.117000Ha -3.1837eV n=6 L=0 occ= 0.00 e= -0.882962Ha -24.0266eV n=6 L=1 occ= 0.00 e= -0.626853Ha -17.0575eV n=6 L=2 occ= 0.00 e= -0.303391Ha -8.2557eV Point group symmetry c4v symmetry orbital prototypes generated (SYMDEC) Symmetry orbitals c4v ! nsym ihmi icax nfmt ipr n norb representation 1 36 a1.1 2 8 b1.1 3 8 b2.1 4 21 e.1 5 21 e.2 total number of valence orbitals: 94 PbCNN分子結(jié)構(gòu)為直線型,屬于Cv類型,但DMOL3不能處理某些特殊點(diǎn)群,因此對于這個(gè)分子結(jié)構(gòu)DMOL3按照C4v處理的。上面信息可以看到。 我們機(jī)組采用的是all electrons,即所有原子軌道群等價(jià)處理,機(jī)組信息在DMOL3輸出文件里面已經(jīng)寫的很清楚了,如給出了主量子數(shù)n,角動(dòng)量子數(shù)l以及軌道本征能量,由于是采用DN機(jī)組,因此2s軌道有兩個(gè),即n=2,l=0出現(xiàn)兩次,同理其他軌道,其次是還有極化機(jī)組如2p增加d成分,3d增加4f的成分以改善軌道的各向異性。 通過C4v的點(diǎn)群分析,得到PBCNN分子分子軌道的不可約表示類型和數(shù)目,如36個(gè)A1,8個(gè)B1和21個(gè)E類型。 |
MaterialStudio學(xué)習(xí)使用 | MS資料 | 量子化學(xué)+實(shí)驗(yàn)研究 | 第一性原理 |
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現(xiàn)在利用DMOL3計(jì)算的分子軌道組合系數(shù)來更詳細(xì)的了解HOMO和LUMO的構(gòu)成: 找出屬于E對稱性的28×28的矩陣: Alpha orbitals, symmetry block 4 e.1 Degeneracy: 2 Size: 21 eigenvalue -471.059 -107.984 -91.903 -22.016 -15.036 -5.585 -5.582 -2.947 -0.903 -0.407 occupation 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Pb 1 2p 1 1.000000 0.000000 -0.000001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000005 Pb 1 3p 1 0.000000 -1.000000 -0.000020 -0.000004 0.000003 0.000000 -0.000005 0.000001 -0.000003 0.000053 Pb 1 4p 1 0.000000 -0.000004 0.000003 1.000000 0.000289 0.000000 -0.000089 -0.000027 -0.000053 0.000394 Pb 1 5p 1 0.000000 0.000001 -0.000001 0.000025 -0.000089 0.000000 0.000303 0.999983 -0.003856 0.004045 Pb 1 6p 1 0.000000 0.000000 0.000000 -0.000008 0.000015 0.000000 0.000005 -0.000016 0.000735 -0.021045 Pb 1 6p 1 0.000000 0.000000 0.000000 -0.000004 0.000015 0.000000 -0.000027 0.000145 0.001729 -0.006460 Pb 1 3d 1 0.000001 -0.000020 1.000000 -0.000003 0.000002 0.000000 0.000003 0.000001 0.000000 0.000008 Pb 1 4d 1 0.000000 -0.000003 0.000002 0.000289 -1.000000 0.000000 0.000182 -0.000089 -0.000024 0.000195 Pb 1 5d 1 0.000000 0.000001 0.000000 0.000027 -0.000009 0.000000 -0.000321 0.003548 0.999049 0.017755 Pb 1 6d 1 0.000000 0.000000 0.000000 -0.000011 0.000004 0.000000 0.000086 -0.000478 -0.001665 -0.006275 Pb 1 4f 1 0.000000 0.000005 0.000003 -0.000089 -0.000182 -0.000057 -1.000000 0.000298 -0.000343 0.000165 Pb 1 4f 3 0.000000 0.000000 0.000000 0.000000 0.000000 1.000000 -0.000057 0.000000 0.000000 0.000000 C 2 2p 1 0.000000 0.000000 0.000000 0.000006 -0.000003 0.000000 -0.000042 0.000233 0.012786 -0.226635 C 2 2p 1 0.000000 0.000000 0.000000 -0.000006 0.000003 0.000000 0.000038 -0.000043 0.002804 -0.049677 C 2 3d 1 0.000000 0.000000 0.000000 0.000000 0.000001 0.000000 -0.000002 -0.000089 -0.003458 -0.023662 N 3 2p 1 0.000000 0.000000 0.000000 -0.000003 0.000002 0.000000 0.000017 0.000010 0.000766 -0.692387 N 3 2p 1 0.000000 0.000000 0.000000 0.000003 -0.000003 0.000000 -0.000015 -0.000013 0.000884 -0.059894 N 3 3d 1 0.000000 0.000000 0.000000 0.000001 0.000000 0.000000 -0.000003 -0.000004 -0.000481 -0.009361 N 4 2p 1 0.000000 0.000000 0.000000 0.000001 -0.000001 0.000000 -0.000003 -0.000015 0.000420 -0.417558 N 4 2p 1 0.000000 0.000000 0.000000 -0.000001 0.000001 0.000000 0.000002 0.000017 -0.000140 -0.055438 N 4 3d 1 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000001 0.000004 -0.000164 0.038595 eigenvalue -0.197 -0.124 0.009 0.179 0.207 0.370 0.551 0.858 1.237 2.013 occupation 1.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Pb 1 2p 1 0.000027 0.000014 -0.000043 -0.000048 -0.000019 0.000059 -0.000115 -0.000193 0.000026 -0.000054 Pb 1 3p 1 0.000264 0.000130 -0.000419 -0.000462 -0.000182 0.000567 -0.001106 -0.001858 0.000254 -0.000520 Pb 1 4p 1 0.001946 0.000963 -0.003073 -0.003397 -0.001337 0.004112 -0.008024 -0.013484 0.001932 -0.003647 Pb 1 5p 1 0.018018 0.008664 -0.027181 -0.030211 -0.012304 0.033752 -0.066329 -0.111173 0.020186 -0.024345 Pb 1 6p 1 -0.411073 0.885650 -0.345053 -0.288786 -0.127053 0.238058 -0.448891 -0.668606 0.133409 -0.140812 Pb 1 6p 1 -0.035458 -0.005107 0.070080 -0.249271 0.963226 -0.264544 0.256110 0.200458 0.024076 0.104079 Pb 1 3d 1 0.000033 0.000015 -0.000048 -0.000052 -0.000022 0.000054 -0.000107 -0.000181 0.000043 -0.000026 Pb 1 4d 1 0.000807 0.000394 -0.001190 -0.001288 -0.000521 0.001282 -0.002574 -0.004348 0.001113 -0.000499 Pb 1 5d 1 0.048218 0.019924 -0.056449 -0.058803 -0.027251 0.042646 -0.089555 -0.149590 0.054950 0.001709 Pb 1 6d 1 -0.028341 -0.039285 0.257235 -1.061094 -0.389460 0.308888 -0.527894 -0.666617 0.168169 -0.099041 Pb 1 4f 1 0.000603 0.000241 -0.000783 -0.000877 -0.000413 0.000536 -0.001173 -0.002115 0.001162 0.000620 Pb 1 4f 3 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 C 2 2p 1 -0.621652 -0.286047 0.740306 0.778711 0.373625 -0.042416 0.450171 1.380197 -0.321656 0.704143 C 2 2p 1 0.006408 0.010420 -0.143532 -0.168487 -0.038919 0.569564 -0.981060 -1.569328 0.025572 -0.536666 C 2 3d 1 -0.000733 -0.021273 -0.029980 0.005642 -0.007314 0.018463 -0.015571 -0.006991 0.496669 0.875117 N 3 2p 1 -0.048514 -0.286179 -0.884200 -0.391040 -0.098555 0.067289 0.053680 -1.188095 0.072471 -1.273909 N 3 2p 1 -0.004783 0.020307 0.138781 0.096059 0.119480 0.375305 -0.269730 1.907042 -0.076649 0.824725 N 3 3d 1 0.048719 0.032795 0.000913 -0.027325 -0.009241 0.021570 0.139273 0.000239 -0.541033 0.064369 N 4 2p 1 0.563077 0.494505 0.662928 0.195219 0.068405 0.120122 -0.268519 0.686731 0.189023 0.508159 N 4 2p 1 -0.011970 -0.043143 -0.138813 -0.077729 0.000309 0.541288 0.929885 -0.790884 0.152217 -0.524453 N 4 3d 1 -0.013571 -0.002980 0.017532 0.013537 -0.005503 -0.043483 -0.018407 0.011014 0.431421 -0.846835 eigenvalue 2.973 occupation 0.00 Pb 1 2p 1 0.000001 Pb 1 3p 1 0.000011 Pb 1 4p 1 0.000162 Pb 1 5p 1 0.004922 Pb 1 6p 1 0.011384 Pb 1 6p 1 0.052461 Pb 1 3d 1 0.000017 Pb 1 4d 1 0.000497 Pb 1 5d 1 0.026927 Pb 1 6d 1 0.016543 Pb 1 4f 1 0.000845 Pb 1 4f 3 0.000000 C 2 2p 1 0.391487 C 2 2p 1 0.041567 C 2 3d 1 0.698990 N 3 2p 1 0.243798 N 3 2p 1 -0.127067 N 3 3d 1 1.310668 N 4 2p 1 -0.625122 N 4 2p 1 0.196849 N 4 3d 1 0.880931 |
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計(jì)算過程中只計(jì)算了PbCNN的前沿分子軌道,即LUMIO和HUMO附近的軌道,計(jì)算采用開層機(jī)組,即自旋不同去向的電子完全分開處理。這樣子輸出的eigenvectors總共有兩組,在DMOL3里面按照alfa和beta稱呼;如: Alpha orbitals, symmetry block 1 a1.1 Degeneracy: 1 Size: 36 eigenvalue -2903.291 -489.148 -471.059 -116.594 -107.982 -91.903 -25.794 -22.013 -15.035 -14.115 occupation 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Pb 1 1s 0 1.000001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Pb 1 2s 0 0.000000 1.000000 -0.000026 0.000000 0.000000 0.000001 0.000000 0.000000 0.000000 -0.000003 Pb 1 3s 0 0.000000 0.000000 0.000000 -1.000000 0.000046 0.000034 0.000003 0.000003 -0.000004 -0.000010 Pb 1 4s 0 0.000000 0.000000 0.000000 -0.000002 -0.000003 -0.000002 -0.999998 0.000575 -0.000198 -0.000031 Pb 1 5s 0 0.000000 0.000000 0.000000 0.000001 0.000001 0.000000 -0.000007 -0.000063 0.000073 -0.000097 Pb 1 6s 0 0.000000 0.000001 0.000000 0.000001 0.000000 0.000000 0.000020 0.000014 0.000012 -0.000232 Pb 1 6s 0 0.000000 0.000000 0.000000 -0.000001 0.000000 0.000000 -0.000001 0.000008 -0.000016 0.000042 Pb 1 2p 0 0.000000 0.000026 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Pb 1 3p 0 0.000000 0.000000 0.000000 -0.000046 -1.000000 0.000001 0.000003 0.000000 0.000002 -0.000001 Pb 1 4p 0 0.000000 0.000000 0.000000 -0.000003 0.000000 0.000002 -0.000574 -1.000000 0.000202 -0.000007 Pb 1 5p 0 0.000000 0.000000 0.000000 0.000001 0.000000 0.000000 -0.000034 0.000006 -0.000091 -0.000049 Pb 1 6p 0 0.000000 0.000001 0.000000 0.000001 0.000000 0.000000 0.000022 0.000003 0.000035 -0.000169 Pb 1 6p 0 0.000000 0.000000 0.000000 -0.000001 0.000000 0.000000 0.000010 -0.000004 0.000013 -0.000006 Pb 1 3d 0 0.000000 -0.000001 0.000000 0.000034 0.000001 1.000000 -0.000002 0.000002 0.000001 0.000000 Pb 1 4d 0 0.000000 0.000000 0.000000 0.000005 -0.000002 0.000001 0.000200 -0.000202 -1.000000 -0.000001 Pb 1 5d 0 0.000000 0.000000 0.000000 -0.000001 0.000000 0.000000 0.000012 -0.000031 0.000000 -0.000025 Pb 1 6d 0 0.000000 0.000000 0.000000 0.000001 0.000000 0.000000 0.000002 0.000012 0.000011 -0.000048 Pb 1 4f 0 0.000000 0.000000 0.000000 0.000002 0.000006 0.000002 0.000028 0.000106 -0.000170 0.000000 C 2 1s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000002 -0.000001 -0.000004 0.000012 C 2 2s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000011 -0.000007 -0.000023 0.000001 C 2 2s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000006 0.000003 0.000013 0.000164 C 2 2p 0 -0.000001 0.000001 0.000000 0.000001 0.000000 0.000000 0.000019 -0.000001 0.000019 -0.000237 C 2 2p 0 0.000000 -0.000001 0.000000 -0.000001 0.000000 0.000000 -0.000014 0.000001 -0.000014 0.000381 C 2 3d 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000003 0.000002 -0.000001 0.000043 N 3 1s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000002 0.000001 -0.000001 -1.000004 N 3 2s 0 0.000000 -0.000001 0.000000 -0.000001 0.000000 0.000000 -0.000012 0.000004 -0.000008 -0.000642 N 3 2s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000007 -0.000002 0.000004 -0.000447 N 3 2p 0 0.000000 0.000000 0.000000 0.000001 0.000000 0.000000 -0.000004 0.000002 -0.000002 -0.000417 N 3 2p 0 0.000000 0.000000 0.000000 -0.000001 0.000000 0.000000 0.000004 -0.000002 0.000002 0.000032 N 3 3d 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000615 N 4 1s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000001 -0.000001 0.000001 -0.004524 N 4 2s 0 0.000000 0.000000 0.000000 -0.000001 0.000000 0.000000 0.000005 -0.000004 0.000003 0.000489 N 4 2s 0 0.000000 0.000000 0.000000 0.000001 0.000000 0.000000 -0.000002 0.000002 -0.000001 -0.000049 N 4 2p 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000002 0.000002 -0.000001 -0.000287 N 4 2p 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000001 -0.000001 0.000000 0.000016 N 4 3d 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000085 eigenvalue -14.049 -9.935 -5.582 -4.211 -2.941 -0.981 -0.909 -0.751 -0.443 -0.373 occupation 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Pb 1 1s 0 -0.000001 0.000000 0.000000 0.000000 0.000001 -0.000033 -0.000014 -0.000070 -0.000175 0.000065 Pb 1 2s 0 -0.000005 -0.000002 0.000001 -0.000001 0.000005 -0.000207 -0.000085 -0.000437 -0.001090 0.000402 Pb 1 3s 0 -0.000016 -0.000006 0.000005 -0.000003 0.000017 -0.000704 -0.000297 -0.001495 -0.003745 0.001371 Pb 1 4s 0 -0.000048 -0.000020 0.000036 0.000006 0.000008 -0.002138 -0.000956 -0.004613 -0.011813 0.004180 Pb 1 5s 0 -0.000150 -0.000074 -0.000056 -0.999991 -0.006868 -0.007073 -0.003108 -0.016648 -0.046660 0.013934 Pb 1 6s 0 -0.000313 -0.000166 0.000065 -0.000131 0.001004 -0.013979 -0.001240 -0.002760 0.556752 -0.176979 Pb 1 6s 0 0.000000 -0.000027 0.000014 -0.000028 0.000595 0.006438 0.002079 0.008658 0.047226 -0.016844 Pb 1 2p 0 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000007 -0.000007 -0.000019 -0.000065 0.000016 |
|
Pb 1 3p 0 -0.000001 -0.000001 0.000007 -0.000001 0.000000 -0.000070 -0.000066 -0.000184 -0.000635 0.000152 Pb 1 4p 0 -0.000010 -0.000008 0.000108 0.000063 0.000006 -0.000506 -0.000540 -0.001356 -0.004753 0.001105 Pb 1 5p 0 -0.000070 -0.000065 -0.000313 -0.006959 0.999899 -0.004483 -0.010067 -0.012952 -0.048206 0.009334 Pb 1 6p 0 -0.000167 -0.000123 0.000051 -0.000089 -0.000015 -0.011888 0.002604 -0.005100 0.114560 0.013067 Pb 1 6p 0 -0.000079 -0.000095 0.000051 -0.000048 0.000096 0.004414 0.006003 0.004380 0.053163 -0.012463 Pb 1 3d 0 0.000000 0.000000 -0.000002 0.000000 0.000000 -0.000004 -0.000007 -0.000013 -0.000060 0.000010 Pb 1 4d 0 -0.000002 -0.000003 -0.000169 -0.000064 -0.000101 -0.000089 -0.000199 -0.000339 -0.001522 0.000251 Pb 1 5d 0 -0.000025 -0.000052 0.000358 0.001275 0.004233 0.018240 0.987400 -0.062027 -0.119149 0.011756 Pb 1 6d 0 0.000001 -0.000010 -0.000072 -0.000200 -0.000449 -0.004661 -0.002852 -0.001816 0.004956 0.010180 Pb 1 4f 0 0.000000 -0.000001 1.000000 -0.000082 0.000317 -0.000046 -0.000506 -0.000176 -0.001011 0.000137 C 2 1s 0 0.000018 1.000604 0.000002 0.000070 -0.000370 -0.025865 -0.005991 -0.031694 0.002655 0.015746 C 2 2s 0 0.000170 0.003736 0.000051 -0.000350 0.001802 0.078289 0.067898 0.463982 0.492064 0.158145 C 2 2s 0 -0.000195 -0.000630 -0.000012 -0.000009 0.000059 0.020385 0.003234 0.014639 -0.028738 -0.023129 C 2 2p 0 -0.000740 0.002131 0.000096 0.000060 -0.000413 0.046109 -0.035041 0.195024 -0.316178 0.173721 C 2 2p 0 0.000420 0.000534 -0.000085 0.000198 -0.001202 0.042013 -0.012167 0.095339 -0.068414 -0.002376 C 2 3d 0 -0.000198 0.000877 -0.000002 -0.000216 0.000697 0.011237 0.008082 0.031459 0.002267 0.005989 N 3 1s 0 0.005386 -0.000568 -0.000019 0.000027 -0.000223 -0.042286 0.000538 -0.003266 -0.006373 -0.004531 N 3 2s 0 0.003421 -0.002180 -0.000116 0.000140 -0.001258 0.587172 -0.011543 0.332116 -0.247314 -0.254602 N 3 2s 0 -0.001346 0.000928 0.000061 -0.000048 0.000574 0.045681 -0.000714 0.002088 0.004379 -0.001417 N 3 2p 0 0.002045 0.002080 -0.000013 -0.000190 0.000016 0.108831 -0.010677 -0.382817 0.101251 -0.175834 N 3 2p 0 -0.001196 -0.001530 0.000018 0.000111 0.000133 0.073837 -0.007473 -0.182701 0.010477 -0.148599 N 3 3d 0 0.000743 -0.000441 -0.000004 0.000036 -0.000125 0.034496 -0.001339 0.005245 -0.000596 0.003109 N 4 1s 0 -1.000586 -0.000127 0.000008 0.000020 0.000078 -0.032842 0.000895 0.002727 0.003682 0.012667 N 4 2s 0 -0.003599 -0.000768 0.000041 0.000134 0.000383 0.441825 -0.023415 -0.427616 0.204500 0.663171 N 4 2s 0 0.001204 0.000473 -0.000014 -0.000094 -0.000112 0.026813 0.000336 0.011988 -0.006973 -0.027607 N 4 2p 0 0.002696 -0.000127 -0.000018 -0.000043 -0.000200 -0.215594 0.009983 0.134412 0.066942 0.587990 N 4 2p 0 0.000423 0.000074 0.000007 0.000043 0.000070 -0.065708 0.002292 0.029605 0.003938 0.042314 N 4 3d 0 -0.000677 0.000145 0.000002 0.000002 0.000040 0.028367 -0.001120 -0.014216 -0.004585 -0.037661 eigenvalue -0.270 -0.004 0.108 0.157 0.201 0.317 0.366 0.396 0.625 0.975 occupation 1.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 0.00 Pb 1 1s 0 -0.000215 -0.000469 -0.001576 -0.001648 -0.000736 0.000471 0.000195 -0.001518 -0.000123 -0.000007 Pb 1 2s 0 -0.001343 -0.002921 -0.009816 -0.010262 -0.004580 0.002936 0.001222 -0.009453 -0.000767 -0.000051 Pb 1 3s 0 -0.004603 -0.009983 -0.033422 -0.034952 -0.015579 0.010076 0.004257 -0.032192 -0.002588 -0.000260 Pb 1 4s 0 -0.014356 -0.030775 -0.101287 -0.106062 -0.047028 0.031604 0.014177 -0.097630 -0.007557 -0.001949 Pb 1 5s 0 -0.053607 -0.108098 -0.325695 -0.343325 -0.148218 0.119304 0.066931 -0.315171 -0.019664 -0.024605 Pb 1 6s 0 -0.806382 -0.509000 -0.869985 -0.977854 -0.395219 0.560994 0.507338 -0.830297 0.126602 -0.285567 Pb 1 6s 0 0.038823 0.038624 0.991744 -0.189980 0.297281 -0.300951 -0.555163 0.005647 -0.473471 0.299077 Pb 1 2p 0 -0.000071 -0.000135 -0.000350 -0.000375 -0.000151 0.000172 0.000122 -0.000340 -0.000001 -0.000084 Pb 1 3p 0 -0.000689 -0.001298 -0.003363 -0.003604 -0.001447 0.001663 0.001191 -0.003268 -0.000005 -0.000819 Pb 1 4p 0 -0.005124 -0.009512 -0.024082 -0.025862 -0.010279 0.012312 0.009034 -0.023471 -0.000018 -0.006256 Pb 1 5p 0 -0.048177 -0.083307 -0.183788 -0.199123 -0.075514 0.113068 0.092261 -0.181354 0.001865 -0.064170 Pb 1 6p 0 0.391035 -1.064457 -0.750256 -0.936441 -0.357130 0.828232 0.889182 -0.703783 0.348183 -0.532266 Pb 1 6p 0 0.053570 0.175959 0.351847 0.543914 -0.645262 0.106339 -0.424835 -0.404975 -0.605047 0.252786 Pb 1 3d 0 -0.000059 -0.000094 -0.000183 -0.000197 -0.000063 0.000144 0.000122 -0.000184 -0.000011 -0.000089 Pb 1 4d 0 -0.001466 -0.002321 -0.004303 -0.004633 -0.001456 0.003569 0.003067 -0.004354 -0.000304 -0.002234 Pb 1 5d 0 -0.095778 -0.103413 -0.119796 -0.138088 -0.031641 0.149072 0.142711 -0.128392 -0.004681 -0.091288 Pb 1 6d 0 0.045885 0.328729 -0.289157 -0.872216 -0.248766 0.873244 0.961331 -0.231146 0.381793 -0.421805 Pb 1 4f 0 -0.000907 -0.001134 -0.001537 -0.001624 -0.000225 0.001996 0.001849 -0.001737 -0.000653 -0.001218 C 2 1s 0 0.008591 0.048923 -0.058307 -0.034712 -0.073554 -0.352634 -0.242651 -0.236120 -0.032242 -0.025204 C 2 2s 0 0.446198 0.705086 -0.280494 0.064095 -0.064020 -2.089160 -1.453100 -1.252611 -0.514293 0.145097 C 2 2s 0 -0.027908 -0.101433 0.146324 0.064646 0.181109 0.583287 0.571529 0.319575 0.547921 -0.858142 C 2 2p 0 -0.308533 -0.358562 -1.243367 -1.104223 -0.333700 0.141495 0.017172 -1.855548 -0.730173 -0.217615 C 2 2p 0 -0.024444 0.093319 0.878145 0.890305 0.529815 0.105535 0.338578 0.703796 0.225262 -0.638990 C 2 3d 0 -0.007692 -0.022885 0.021864 -0.021971 -0.066244 -0.012955 -0.041213 -0.009210 0.158899 0.061965 N 3 1s 0 -0.008000 -0.017928 0.167259 0.074013 -0.083873 -0.186240 0.258968 0.188887 0.062183 0.017023 N 3 2s 0 -0.146461 -0.223741 1.062128 0.350670 -0.763469 -1.048249 1.400593 1.418060 0.328613 0.067170 N 3 2s 0 0.005407 0.011504 -0.323729 -0.130976 0.155113 0.418059 -0.304557 -0.290916 -0.033112 -0.079261 N 3 2p 0 0.113150 -0.032620 -0.786344 -0.964252 -0.707164 -1.368678 0.223496 -1.133403 0.045128 -1.138735 N 3 2p 0 0.048966 0.138684 0.483526 0.734150 0.624686 0.843271 -0.023952 1.044047 -0.952418 0.388802 N 3 3d 0 0.002201 0.016132 0.031883 0.062304 0.088235 -0.026608 0.124767 -0.142504 0.032375 0.027471 N 4 1s 0 0.002041 0.027746 0.085843 0.160534 0.174526 0.287620 -0.099363 0.176019 -0.074664 0.087975 N 4 2s 0 -0.008159 0.198331 0.532661 1.035563 1.188120 1.807735 -0.677799 0.861317 -0.226987 0.395121 N 4 2s 0 -0.003071 -0.052580 -0.171658 -0.281936 -0.271890 -0.541472 0.394683 -0.333169 -0.064618 0.450286 N 4 2p 0 -0.111070 -0.139437 -0.041760 -0.366808 -0.664352 -0.938490 0.693686 0.211573 -0.438938 -0.051118 N 4 2p 0 -0.004360 0.025276 0.050436 0.180699 0.297579 0.948081 -0.839837 0.455073 0.097901 -0.721704 N 4 3d 0 0.005728 0.004314 0.010720 0.019933 0.008659 0.027904 0.019500 0.116874 -0.169805 -0.036178 |
|
eigenvalue 1.157 1.535 1.829 2.198 2.546 4.028 occupation 0.00 0.00 0.00 0.00 0.00 0.00 Pb 1 1s 0 -0.006325 0.001014 -0.000776 0.002138 -0.000140 -0.001179 Pb 1 2s 0 -0.039382 0.006305 -0.004840 0.013316 -0.000866 -0.007331 Pb 1 3s 0 -0.134131 0.021294 -0.016587 0.045444 -0.002848 -0.024833 Pb 1 4s 0 -0.406974 0.062244 -0.051670 0.139126 -0.007294 -0.073544 Pb 1 5s 0 -1.311311 0.165373 -0.184570 0.467608 -0.003304 -0.209828 Pb 1 6s 0 -3.500289 0.073364 -0.556386 1.290089 0.077565 -0.373648 Pb 1 6s 0 1.064711 0.283568 0.109339 -0.314328 -0.011467 0.026767 Pb 1 2p 0 -0.001460 0.000067 -0.000274 0.000564 0.000055 -0.000157 Pb 1 3p 0 -0.014018 0.000624 -0.002643 0.005434 0.000541 -0.001486 Pb 1 4p 0 -0.100236 0.003763 -0.019213 0.039488 0.004405 -0.009947 Pb 1 5p 0 -0.751178 0.000583 -0.154202 0.317725 0.051694 -0.050188 Pb 1 6p 0 -3.052634 -0.388058 -0.576638 1.208182 0.197580 -0.086956 Pb 1 6p 0 0.362843 0.275750 -0.057555 -0.018507 0.037098 -0.014329 Pb 1 3d 0 -0.000748 -0.000058 -0.000218 0.000373 0.000104 0.000007 Pb 1 4d 0 -0.017360 -0.001583 -0.005166 0.008996 0.002699 0.000456 Pb 1 5d 0 -0.417660 -0.083415 -0.132382 0.249614 0.090683 0.044524 Pb 1 6d 0 -1.140056 -0.447036 -0.276269 0.497131 0.147950 0.109642 Pb 1 4f 0 -0.004627 -0.001130 -0.002012 0.004383 0.002130 0.001472 C 2 1s 0 -0.006326 0.791762 0.998959 0.076767 -0.273222 -0.808528 C 2 2s 0 0.614608 4.424624 5.237719 -0.121532 -1.636295 -3.795518 C 2 2s 0 -1.403464 -2.187275 -2.209993 0.509685 0.752262 0.839596 C 2 2p 0 -3.631827 2.187264 0.997602 1.097136 -0.831246 -2.667038 C 2 2p 0 3.068524 -1.423093 -0.057666 -0.892039 0.349331 0.773009 C 2 3d 0 -0.209194 0.135255 0.101068 -0.928796 -0.716920 -0.792000 N 3 1s 0 0.299065 -0.779693 0.368579 0.235064 -0.228414 0.996024 N 3 2s 0 1.810772 -4.851546 2.073946 0.799072 -0.983440 6.062178 N 3 2s 0 -1.106929 3.417787 -1.050156 0.409484 0.120782 -2.968144 N 3 2p 0 -1.611174 1.373277 5.310226 0.886720 -1.989025 -0.539507 N 3 2p 0 1.141439 -1.185296 -4.554767 -0.895829 0.436510 0.528195 N 3 3d 0 -0.097863 0.151386 0.107439 -0.320644 -0.024596 1.887728 N 4 1s 0 0.226233 0.087949 -1.085947 -0.160292 0.313070 -0.525249 N 4 2s 0 1.444795 0.616939 -6.325964 -1.204327 2.080676 -2.545967 N 4 2s 0 -1.179420 -0.554126 3.749126 0.973804 -1.250612 0.609137 N 4 2p 0 -0.503003 -0.659461 2.160975 0.615980 -1.392882 1.730846 N 4 2p 0 0.268475 0.708499 -1.077237 -0.511508 0.742517 -0.373331 N 4 3d 0 -0.129939 0.092432 0.024794 -0.615399 1.147032 -0.608347 這個(gè)是屬于A1的36個(gè)分子軌道組成的36×36的矩陣,屬于alfa自旋通道; beta如下: Beta orbitals, symmetry block 1 a1.1 Degeneracy: 1 Size: 36 eigenvalue -2903.291 -489.148 -471.059 -116.594 -107.982 -91.903 -25.794 -22.013 -15.035 -14.115 occupation 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 1.00 Pb 1 1s 0 1.000001 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Pb 1 2s 0 0.000000 1.000000 -0.000026 0.000000 0.000000 0.000001 0.000000 0.000000 0.000000 -0.000003 Pb 1 3s 0 0.000000 0.000000 0.000000 -1.000000 0.000046 0.000034 0.000003 0.000003 -0.000004 -0.000010 Pb 1 4s 0 0.000000 0.000000 0.000000 -0.000002 -0.000003 -0.000002 -0.999998 0.000575 -0.000198 -0.000031 Pb 1 5s 0 0.000000 0.000000 0.000000 0.000001 0.000001 0.000000 -0.000007 -0.000063 0.000073 -0.000097 Pb 1 6s 0 0.000000 0.000001 0.000000 0.000001 0.000000 0.000000 0.000020 0.000014 0.000012 -0.000232 Pb 1 6s 0 0.000000 0.000000 0.000000 -0.000001 0.000000 0.000000 -0.000001 0.000008 -0.000016 0.000042 Pb 1 2p 0 0.000000 0.000026 1.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 Pb 1 3p 0 0.000000 0.000000 0.000000 -0.000046 -1.000000 0.000001 0.000003 0.000000 0.000002 -0.000001 Pb 1 4p 0 0.000000 0.000000 0.000000 -0.000003 0.000000 0.000002 -0.000574 -1.000000 0.000202 -0.000007 Pb 1 5p 0 0.000000 0.000000 0.000000 0.000001 0.000000 0.000000 -0.000034 0.000006 -0.000091 -0.000049 Pb 1 6p 0 0.000000 0.000001 0.000000 0.000001 0.000000 0.000000 0.000022 0.000003 0.000035 -0.000169 Pb 1 6p 0 0.000000 0.000000 0.000000 -0.000001 0.000000 0.000000 0.000010 -0.000004 0.000013 -0.000006 Pb 1 3d 0 0.000000 -0.000001 0.000000 0.000034 0.000001 1.000000 -0.000002 0.000002 0.000001 0.000000 Pb 1 4d 0 0.000000 0.000000 0.000000 0.000005 -0.000002 0.000001 0.000200 -0.000202 -1.000000 -0.000001 Pb 1 5d 0 0.000000 0.000000 0.000000 -0.000001 0.000000 0.000000 0.000012 -0.000031 0.000000 -0.000025 Pb 1 6d 0 0.000000 0.000000 0.000000 0.000001 0.000000 0.000000 0.000002 0.000012 0.000011 -0.000048 Pb 1 4f 0 0.000000 0.000000 0.000000 0.000002 0.000006 0.000002 0.000028 0.000106 -0.000170 0.000000 C 2 1s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000002 -0.000001 -0.000004 0.000012 C 2 2s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000011 -0.000007 -0.000023 0.000001 C 2 2s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000006 0.000003 0.000013 0.000164 C 2 2p 0 -0.000001 0.000001 0.000000 0.000001 0.000000 0.000000 0.000019 -0.000001 0.000019 -0.000237 C 2 2p 0 0.000000 -0.000001 0.000000 -0.000001 0.000000 0.000000 -0.000014 0.000001 -0.000014 0.000381 C 2 3d 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000003 0.000002 -0.000001 0.000043 N 3 1s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000002 0.000001 -0.000001 -1.000004 N 3 2s 0 0.000000 -0.000001 0.000000 -0.000001 0.000000 0.000000 -0.000012 0.000004 -0.000008 -0.000642 N 3 2s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000007 -0.000002 0.000004 -0.000447 N 3 2p 0 0.000000 0.000000 0.000000 0.000001 0.000000 0.000000 -0.000004 0.000002 -0.000002 -0.000417 N 3 2p 0 0.000000 0.000000 0.000000 -0.000001 0.000000 0.000000 0.000004 -0.000002 0.000002 0.000032 N 3 3d 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000615 N 4 1s 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000001 -0.000001 0.000001 -0.004524 N 4 2s 0 0.000000 0.000000 0.000000 -0.000001 0.000000 0.000000 0.000005 -0.000004 0.000003 0.000489 N 4 2s 0 0.000000 0.000000 0.000000 0.000001 0.000000 0.000000 -0.000002 0.000002 -0.000001 -0.000049 N 4 2p 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 -0.000002 0.000002 -0.000001 -0.000287 N 4 2p 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000001 -0.000001 0.000000 0.000016 N 4 3d 0 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000000 0.000085 |
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