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被風(fēng)掠過(guò)金蟲(chóng) (正式寫手)
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[求助]
文獻(xiàn)翻譯求助,英翻漢
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Structure of [Cd(Tipa)(L1)2] 3 H2O (1). Compound 1 contains one crystallographically unique CdII atom, two unique L1 anions, and one Tipa ligand (Figure 1a). The CdII atom is six-coordinated by three nitrogen atoms from three different Tipa ligands [Cd1N3 = 2.307(3), Cd1N6#1 = 2.306(3), and Cd1N7#2 =2.359(3) Å], and three oxygen atoms from two different L1 anions [Cd1O1 = 2.704(5), Cd1O2 = 2.260(2), and Cd1O3 = 2.253(2) Å] in a distorted octahedral geometry. The CdIIO and CdIIN distances are similar to the previously reported ones.10 The Tipa ligands in trimonodentate modes bridge adjacent CdII atoms to give an infinite 1D chain(Figure 1b). Two types of L1 anions are attached on both sidesof the chain. |

木蟲(chóng) (著名寫手)
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非化學(xué)本行,淺嘗翻譯... Structure of [Cd(Tipa)(L1)2] 3 H2O (1). Compound 1 contains one crystallographically unique CdII atom, two unique L1 anions, and one Tipa ligand (Figure 1a). The CdII atom is six-coordinated by three nitrogen atoms from three different Tipa ligands [Cd1N3 = 2.307(3), Cd1N6#1 = 2.306(3), and Cd1N7#2 =2.359(3) Å], and three oxygen atoms from two different L1 anions [Cd1O1 = 2.704(5), Cd1O2 = 2.260(2), and Cd1O3 = 2.253(2) Å] in a distorted octahedral geometry. The CdIIO and CdIIN distances are similar to the previously reported ones.10 The Tipa ligands in trimonodentate modes bridge adjacent CdII atoms to give an infinite 1D chain(Figure 1b). Two types of L1 anions are attached on both sidesof the chain. [Cd(Tipa)(L1)2] 3 H2O (1)結(jié)構(gòu);衔1包括1個(gè)結(jié)晶狀的獨(dú)特 CdII 原子,2個(gè)獨(dú)特的 L1 陰離子和一個(gè)Tipa(三異丙醇胺?)配位(圖1a)。 CdII原子是1個(gè)變形八面體幾何結(jié)構(gòu)的六配位,通過(guò)來(lái)自3個(gè)不同Tipa配位[Cd1N3 = 2.307(3), Cd1N6#1 = 2.306(3), and Cd1N7#2 =2.359(3) Å]的3個(gè)氮原子以及來(lái)自2個(gè)不同L1陰離子的3個(gè)氧原子而得到。CdIIO與CdII的間距相似于前面提到的間距。10(這個(gè)數(shù)字是什么?) 三重單配位模式橋結(jié)點(diǎn)CdII原子的Tipa配位, 給出一個(gè)無(wú)限的1D鏈(圖1b)(個(gè)人認(rèn)為原文這句話是不是缺少謂語(yǔ),或者結(jié)合前面出現(xiàn)的數(shù)字‘10’是一個(gè)標(biāo)題?)。兩種類型的L1陰離子連附于鏈的雙面。 |
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