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xiaoliuer金蟲(chóng) (小有名氣)
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[求助]
審稿意見(jiàn)關(guān)于晶體結(jié)構(gòu)問(wèn)題求助,在線等
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文章審稿意見(jiàn)回來(lái)了,審稿人提了幾個(gè)關(guān)于晶體數(shù)據(jù)的問(wèn)題,請(qǐng)問(wèn)該怎么改? 1 many reported and calculated angles do not match at all。 2 In any case, both of your structures have large voids, and the use of SQUEEZE is not reported in the cif file in the customary way by including the cif loop resulting from the SQUEEZE process. This must be included, and must contain the number and nature of the squeezed-out entities (I would also welcome a note about this in the _refine_special_details section). Currently, there is also no mention of the use of SQUEEZE in the main paper. 3 The number of restraints is reported as 8, but no details about these restraints were given in the _refine_special_details section of the cif file. This information can also be provided by making use of the restraint CIF dictionary items. |
金蟲(chóng) (小有名氣)
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1. 你的很多report的鍵角和計(jì)算的不一樣。 可能是你做了什么限制導(dǎo)致的。 2. 你的結(jié)構(gòu)中存在空隙, 可能有溶劑分子,而且你沒(méi)有說(shuō)明有沒(méi)有用SQUEEZE。如果用了,把詳細(xì)信息寫(xiě)到cif里面。 (去蟲(chóng)子上搜How to use squeeze). 3. 你report了8個(gè)限制, 但是你沒(méi)有具體說(shuō)明都是什么限制, 比如鍵長(zhǎng)或者坐標(biāo)什么的。 |


金蟲(chóng) (小有名氣)
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_refine_special_details ; Refinement of F^2^ against ALL reflections. The weighted R-factor wR and goodness of fit S are based on F^2^, conventional R-factors R are based on F, with F set to zero for negative F^2^. The threshold expression of F^2^ > 2sigma(F^2^) is used only for calculating R-factors(gt) etc. and is not relevant to the choice of reflections for refinement. R-factors based on F^2^ are statistically about twice as large as those based on F, and R- factors based on ALL data will be even larger. 是加在這些下面是嗎? dfix 1.56 0.02 c22 c21 dfix 1.45 0.02 c22 c23我直接把這樣的限制加下面就可以是嗎? |
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