 |
 |
 |
 |
 |
 |
||
 |
 |
 |
 |
 |
| 6 | 1/1 | 返回列表 |
| 查看: 805 | 回復(fù): 5 | |||
養(yǎng)只狗叫啊貓金蟲 (正式寫手)
|
[交流]
求幫助翻譯一段話 已有2人參與
|
|
各位高手，誰能幫我翻譯下這段文字啊，看得太累了，謝謝了 Therefore, 1H-benz- imidazole-5,6-dicarboxylic acid (H3bidc) is an outstanding candidate ligand to construct d–f HMCPs as it is a multidentate rigid ligand with O-donors and N-donors and possesses diverse coordination modes with different metal ions. Moreover, the distance between the N-donors and O-donors in H3bidc is large enough to overcome steric hindrance. In addition H3bidc can be used to assemble HMCPs with interpene- trated frameworks. Our group reported Ln–Ag HMCPs with doubly interpenetrated frameworks constructed from the H3bidc ligand。 To the best of our knowledge, 3d–4f HMCPs constructed by H3bidc ligands have not yet been reported, although 3d–4f HMCPs have been widely investigated, of which most are Cu–Ln systems.11 However, the number of reported Ni–Ln HMCPs is relatively limited and they are mainly cluster com- plexes or low-dimensional complexes.12 Therefore, the synthesis of higher dimensional Ni–Ln HMCPs complexes is of great importance. Based on the above-mentioned points, our aim is to synthesize 3d–4f HMCPs with novel frameworks bearing noteworthy prop- erties by using NiSO •7H O, rare earth oxides and H bidc ligands. Herein, we report the synthesis, structural characteriz- ation and properties of a family of [Ln2Ni(Hbidc)2(SO4)2- (H2O)8]n HMCPs [Ln = Pr (1), Sm (2), Eu (3), Gd (4), Tb (5), Dy (6), Ho (7), Er (8), Yb (9)]. Structure determination revealed that all compounds have a three-dimensional network and the lanthanide contraction has a significant influence on the structure transformation. The luminescence properties of HMCPs 1–9 were studied, and several of the HMCPs exhibit the characteristic transitions of the corresponding lanthanide ions. The magnetic properties of HMCPs 4 and 6–8 were measured, revealing that ferromagnetic coupling is present in 4. [ Last edited by winter_north on 2013-2-20 at 00:06 ] |
回復(fù)此樓» 猜你喜歡
298求調(diào)劑
已經(jīng)有7人回復(fù)
-
263求調(diào)劑
已經(jīng)有5人回復(fù)
-
276求調(diào)劑。有半年電池和半年高分子實習(xí)經(jīng)歷
已經(jīng)有6人回復(fù)
-
求調(diào)劑材料學(xué)碩080500，總分289分
已經(jīng)有21人回復(fù)
-
北科281學(xué)碩材料求調(diào)劑
已經(jīng)有8人回復(fù)
-
2026化學(xué)調(diào)劑
已經(jīng)有3人回復(fù)
-
08工學(xué)調(diào)劑
已經(jīng)有9人回復(fù)
-
291 求調(diào)劑
已經(jīng)有4人回復(fù)
-
070300化學(xué)求調(diào)劑
已經(jīng)有5人回復(fù)
-
085600材料與化工
已經(jīng)有10人回復(fù)
» 本主題相關(guān)價值貼推薦，對您同樣有幫助:
- 急求翻譯一段話
已經(jīng)有1人回復(fù)
- 求助翻譯一段話，謝謝
已經(jīng)有3人回復(fù)
- 求助翻譯一段話
已經(jīng)有1人回復(fù)
- 求助翻譯一段話
已經(jīng)有1人回復(fù)
- 求助翻譯一段話
已經(jīng)有1人回復(fù)
- 求助翻譯一段話
已經(jīng)有7人回復(fù)
- 急求翻譯一段話
已經(jīng)有4人回復(fù)
- 求助翻譯一段話
已經(jīng)有1人回復(fù)
- 求助翻譯一段話，謝謝��！
已經(jīng)有2人回復(fù)
- 求助翻譯一段話
已經(jīng)有4人回復(fù)
- 求助翻譯一段話
已經(jīng)有1人回復(fù)
- 求助翻譯一段話。先謝謝了！
已經(jīng)有3人回復(fù)
- 求翻譯一段話
已經(jīng)有2人回復(fù)
- 求助翻譯一段話，謝謝！
已經(jīng)有3人回復(fù)
- 求助翻譯一段話
已經(jīng)有2人回復(fù)
- 求助翻譯一段話
已經(jīng)有2人回復(fù)
★
小木蟲: 沙發(fā)+1，金幣+0.5, 恭喜搶個沙發(fā)，再給個紅包
小木蟲: 沙發(fā)+1，金幣+0.5, 恭喜搶個沙發(fā)，再給個紅包
 |
2樓2013-02-19 23:45:32
★
小木蟲: 金幣+0.2, 搶了個小板凳，給個紅包
小木蟲: 金幣+0.2, 搶了個小板凳，給個紅包
 [ 發(fā)自手機版 http://www.gaoyang168.com/3g ] |
3樓2013-02-19 23:46:44
4樓2013-02-20 16:06:46
5樓2013-02-20 16:08:01
|
To the best of our knowledge, 3d–4f HMCPs constructed by H3bidc ligands have not yet been reported, although 3d–4f HMCPs have been widely investigated, of which most are Cu–Ln systems.11 However, the number of reported Ni–Ln HMCPs is relatively limited and they are mainly cluster com- plexes or low-dimensional complexes.12 Therefore, the synthesis of higher dimensional Ni–Ln HMCPs complexes is of great importance. 就我們所知，由 H3bidc配體創(chuàng)建起的3d–4f HMCPs還沒有被報道過，盡管3d–4f HMCPs，其中大部分是Cu-Ln體系，已經(jīng)被廣泛研究。然而， 被報道過的Ni-Ln HMCP的數(shù)量相對有限，而且它們主要是簇復(fù)合物或者是低維復(fù)合物。因此，合成高維Ni–Ln HMCPs復(fù)合物是很重要的。 先翻這段，下面的接力。 |
6樓2013-03-21 21:40:20
相關(guān)版塊跳轉(zhuǎn)
我要訂閱樓主 養(yǎng)只狗叫啊貓 的主題更新
| 6 | 1/1 | 返回列表 |
| 最具人氣熱帖推薦 [查看全部] | 作者 | 回/看 | 最后發(fā)表 | |
|---|---|---|---|---|
|
[考研] 352求調(diào)劑 +3 | 大米飯！ 2026-03-22 | 3/150 |
|
|---|---|---|---|---|
|
|
[考研]
 一志愿東華大學(xué)化學(xué)070300，求調(diào)劑
+7
|
2117205181 2026-03-21 | 8/400 |
|
|
|
[考研] 0854電子信息求調(diào)劑 +3 | α____ 2026-03-22 | 3/150 |
|
|
[考研] 328求調(diào)劑，英語六級551，有科研經(jīng)歷 +6 | 生物工程調(diào)劑 2026-03-17 | 10/500 |
|
|
|
[考研] 310求調(diào)劑 +4 | baibai1314 2026-03-16 | 4/200 |
|
|
|
[考研] 資源與環(huán)境 調(diào)劑申請(333分) +5 | holy J 2026-03-21 | 5/250 |
|
|
|
[考研] 材料學(xué)碩333求調(diào)劑 +3 | 北道巷 2026-03-18 | 3/150 |
|
|
|
[考研] 296求調(diào)劑 +4 | www_q 2026-03-20 | 4/200 |
|
|
|
[考研] 22 350 本科985求調(diào)劑，求老登收留 +3 | 李軼男003 2026-03-20 | 3/150 |
|
|
|
[考研] 求調(diào)劑 +6 | Mqqqqqq 2026-03-19 | 6/300 |
|
|
|
[考研] 材料工程（專）一志愿985 初試335求調(diào)劑 +3 | hiloiy 2026-03-17 | 4/200 |
|
|
|
[考研] 求調(diào)劑 +3 | Ma_xt 2026-03-17 | 3/150 |
|
|
|
[考研] 華東師范大學(xué)-071000生物學(xué)-293分-求調(diào)劑 +3 | 研究生何瑤明 2026-03-18 | 3/150 |
|
|
|
[考研] 一志愿華中科技大學(xué)，080502，354分求調(diào)劑 +5 | 守候夕陽CF 2026-03-18 | 5/250 |
|
|
|
[考研] 294求調(diào)劑材料與化工專碩 +15 | 陌の森林 2026-03-18 | 15/750 |
|
|
|
[考研]
295復(fù)試調(diào)劑
+8
|
簡木ChuFront 2026-03-19 | 8/400 |
|
|
|
[考研] 261求B區(qū)調(diào)劑，科研經(jīng)歷豐富 +3 | 牛奶很忙 2026-03-20 | 4/200 |
|
|
|
[考研] 0856調(diào)劑，是學(xué)校就去 +8 | sllhht 2026-03-19 | 9/450 |
|
|
|
[考博] 26博士申請 +3 | 1042136743 2026-03-17 | 3/150 |
|
|
|
[考研] 一志愿蘇州大學(xué)材料工程（085601）專碩有科研經(jīng)歷三項國獎兩個實用型專利一項省級立項 +6 | 大火山小火山 2026-03-16 | 8/400 |
|