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對天空說lrj金蟲 (正式寫手)
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[求助]
請高手幫忙翻譯兩句化學材料方面的英文
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Of the t2g set of orbitals, the 3dxz and 3dyz orbitals point in between the ligands and are involved in π interactions. Since these interactions are weaker, the unfilled antibonding π* states lie closer to the Fermi level at relatively lower energies in the conduction band (correspondingly, the filled π states lie higher in energy in the valence band).請高手解釋一下, |

禁蟲 (知名作家)
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固體物理中的比較專業(yè),不懂。 Of the t2g set of orbitals, the 3dxz and 3dyz orbitals point in between the ligands and are involved in π interactions. Since these interactions are weaker, the unfilled antibonding π* states lie closer to the Fermi level at relatively lower energies in the conduction band (correspondingly, the filled π states lie higher in energy in the valence band) 配體之間的t2g軌道中,3dyz和3dxz軌道和參與π鍵的交互作用。由于這一交互作用比較弱,在導帶中位于低能區(qū)的未飽和反π* 鍵接近費米能級(也就是說,在價帶中的飽和的π 鍵位于較高能級)。 |
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