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對(duì)天空說(shuō)lrj金蟲(chóng) (正式寫(xiě)手)
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[求助]
請(qǐng)高手幫忙翻譯兩句化學(xué)材料方面的英文
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Of the t2g set of orbitals, the 3dxz and 3dyz orbitals point in between the ligands and are involved in π interactions. Since these interactions are weaker, the unfilled antibonding π* states lie closer to the Fermi level at relatively lower energies in the conduction band (correspondingly, the filled π states lie higher in energy in the valence band).請(qǐng)高手解釋一下, |

禁蟲(chóng) (知名作家)
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固體物理中的比較專業(yè),不懂。 Of the t2g set of orbitals, the 3dxz and 3dyz orbitals point in between the ligands and are involved in π interactions. Since these interactions are weaker, the unfilled antibonding π* states lie closer to the Fermi level at relatively lower energies in the conduction band (correspondingly, the filled π states lie higher in energy in the valence band) 配體之間的t2g軌道中,3dyz和3dxz軌道和參與π鍵的交互作用。由于這一交互作用比較弱,在導(dǎo)帶中位于低能區(qū)的未飽和反π* 鍵接近費(fèi)米能級(jí)(也就是說(shuō),在價(jià)帶中的飽和的π 鍵位于較高能級(jí))。 |
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