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without comparing their data using the genuine Ir(III) samples, I must said their data are not verified, particularly under the situation that such substitution effect of xxx (一個(gè)取代基)fragment is relatively small. This is evident in their data the reported difference in distances (cf. Table 1), in percentage of metal characters (cf. Table 3) or even in potentials (or energy level) are all at the hundred place after decimal point. I believe such a small difference should be within the limit of their calculation。 因?yàn)闆](méi)有晶體數(shù)據(jù),所以我用能級(jí)以及吸收波選擇的泛函,我看一些文獻(xiàn)上基本從基態(tài)S0到T1的變化都是小數(shù)點(diǎn)后百分位的,有沒(méi)有相關(guān)文獻(xiàn)什么的,可以說(shuō)明對(duì)于理論計(jì)算,鍵長(zhǎng)這么大的范圍算是比較大的呀? |
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