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zjsxwxl2008木蟲 (正式寫手)
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[求助]
請(qǐng)大神幫忙翻譯一下摘要,謝謝!
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摘 要:用斜式沸點(diǎn)儀測(cè)定了乙烯基三乙氧基硅烷在2.035~71.035kPa范圍內(nèi)的飽和溫度數(shù)據(jù)。采用非線性回歸方法,利用EVIEWS5.0軟件得到乙烯基三乙氧基硅烷的Antoine常數(shù)A,B,C的值分別為10.00842,1985.189和-34.98381,Antoine方程計(jì)算出的飽和溫度與實(shí)驗(yàn)數(shù)據(jù)的絕對(duì)偏差為0.01~1.02K;通過安托尼方程和Clarke & Glew方程對(duì)飽和溫度以及蒸汽壓數(shù)據(jù)進(jìn)行了關(guān)聯(lián)擬合。通過蒸汽壓數(shù)據(jù)與溫度的關(guān)系得到乙烯基三乙氧基硅烷的標(biāo)準(zhǔn)摩爾蒸發(fā)焓 (298.15K)為48.29 kJ mol−1。通過基團(tuán)貢獻(xiàn)發(fā)推算出乙烯基三乙氧基硅烷的臨界溫度、臨界壓強(qiáng)和臨界體積。還用安托尼方程和標(biāo)準(zhǔn)沸點(diǎn)的實(shí)驗(yàn)數(shù)值對(duì)偏心因子進(jìn)行了推算。 關(guān)鍵詞:乙烯基三乙氧基硅烷;飽和蒸汽壓; Antoine方程;Clarke & Glew方程;偏心因子 |
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Abstract: Vinyl triethoxysilane saturation temperature datas of 2.035 ~ 71.035kPa were measured by inclined ebulliometer and vinyl triethoxysilane Antoine constant A, B, and C are 10.00842,1985.189 and -34.98381 by the use of EVIEWS5.0 software for Nonlinear regression analysis. The saturation temperature deviation between the experimental data and that calculated by Antoine equation are of 0.01 ~ 1.02K . The saturation temperature and vapor pressure data correlation were fitted by Antoine equation and Clarke & Glew equation also. Vinyl triethoxysilane standard molar enthalpy of evaporation (298.15K) is 48.29 kJ mol-1 according to the relationship between Vapor pressure and temperature . The critical temperature , the critical pressure and critical volume of vinyltriethoxysilane were calculated by the group contribution method . And eccentric factors by experimental deta of normal boiling point and Antoine equation . Keywords: vinyl triethoxysilane; saturated vapor pressure; Antoine equation; Clarke & Glew equation; eccentric factor |

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it is a good tranlsation. I made minor edits to make it more natural. Abstract: Vinyl triethoxysilane saturation temperatures (STs) of 2.035 ~ 71.035kPa were measured by inclined ebulliometer. vinyl triethoxysilane Antoine constant A, B, and C are respectively 10.00842,1985.189 and -34.98381 by the use of EVIEWS5.0 software for Nonlinear regression analysis. The absolute deviation between the experimental and calculated ST by Antoine equation are of 0.01 ~ 1.02K . The relation between ST and vapor pressure data was fitted by Antoine equation and Clarke & Glew equation. Vinyl triethoxysilane standard molar enthalpy of evaporation (298.15K) is 48.29 kJ mol-1 according to the relationship between Vapor pressure and temperature . The critical temperature , the critical pressure and critical volume of vinyltriethoxysilane were calculated by the group contribution methodology; the eccentric factor was also derived from experimentally obtained standard boiling point and Antoine equation . Keywords: vinyl triethoxysilane; saturated vapor pressure; Antoine equation; Clarke & Glew equation; eccentric factor |
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