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andyzhu木蟲 (正式寫手)
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被這樣的審稿意見拒搞了。
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雖然我知道有自己疏忽的問題,但是相對于第二個審稿人(提出更多實質(zhì)意義的的建議)讓我大修,我還是有點郁悶。哎,運氣不好,還是我沒意識到這些問題有多嚴重,請高手指點迷津。如下。 1. The .cif files do not contain the shelx instructions or the reflection intensities. The .fcf file has also not been provided by the authors. As such, the refinement cannot be independently verified by the reviewer. 沒上傳fcf,是最大的罪過。 2. The text mentions the MOF space group is Pcca, however it is listed as Pccn in the .cif files. 我的錯,眼神不好,寫錯。 3. Page 10, line 208: “Moreover, the presence of trace (CH2)2NH2+ ions used as the counter cations…” Trace ions?!? Isn’t the dimethyl ammonium the counter ion for the structure? I would expect it to be present in stoichiometric proportions, not trace amounts…自己表達不清。 4. The authors claim that the (CH2)2NH2+ ion is the charge balancing cation in the MOF structures, however, the authors present no evidence to support this claim. Given that the authors claim that the cation influences the physical properties of the material (Page 10 line 208), the chemical identity of the cation should be established unambiguously.給我個機會,我可證明,的確 (CH2)2NH2+真實存在。。 5. Several notable entries in the crystal data table (S1) are absent: number of parameters, number of restraints, cell volume, 2-theta range, Rint, hkl limits.我可以補的,但是我的表格就是抄的這個雜志之前table。。 6. None of the datablock names in the .cif files or cifchecks matches the names in the manuscript. This unnecessarily complicates reviewer evaluations.難道我的cif命名為我的CCDC號也是一種錯誤?不解。。 7. The Eu structure contains 12 restraints. No details are given. 之前投稿沒注意這個要。以后大家要注意了,特別是晶體學雜志 8. The H2DDQ structure: H1 does not appear to be in a correctly refined position. Likewise, the protons on the water molecule have not been refined. It seems that they should be added such that they form hydrogen bonds with N2 and O2. 9. Both the Eu and Er structures contain very large residual electron density peaks. The location of the peaks should be mentioned and explained.稀土金屬容易出現(xiàn)鬼峰,我就少說了一句。 10. While MOF datasets are often of poor quality and low resolution/completeness, this should not be the case for well-packed small molecules. Though the completeness is reasonable at 0.977, why is this not closer to 1.0? Was the data collected properly? Was there a problem with the data processing? 完整度0.977在我們學校測試可以了,曝光時間3S, 三斜掃一般700張 11. For all structures, the formulas should be updated to reflect the refined data. Atoms which are not present (for example, Cl and P in the H2DDQ structure) should be removed. 因為體系有這個元素,解的時候定了P Cl了,但是這不至于拒搞吧。 |
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鐵桿木蟲 (文壇精英)

新蟲 (知名作家)
榮譽版主 (文壇精英)

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