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數(shù)理小肥羊銀蟲 (小有名氣)
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[求助]
堿式碳酸鎳的XRD 2theta 度數(shù) 已有1人參與
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在一篇文獻上看到堿式碳酸鎳的XRD符合(JCPDS No.35−0501),想知道它的2theta 度數(shù)? 另外想問,尿素和硝酸鎳會合成醋酸鎳么? 萬分感謝! |
木蟲 (著名寫手)
有木有蟲
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尿素和硝酸鎳可能生成碳酸鎳,但更可能是生成氫氧化鎳或堿式碳酸鎳,這個我信,會生成醋酸鎳我真心不信。 Card Information Names: Nickel Carbonate Hydroxide Nullaginite Formula: Ni2 ( C O3 ) ( O H )2 PDF Number: 35-501 Quality: indexed Subfiles: inorganic mineral COR Cell and Symmetry Information System: monoclinic Space Group: P21/* (no. 11) a: 9.236 b: 12.001 c: 3.091 b: 90.48 Density (Dm): 3.560 Density (Dx): 4.070 Z: 4 Instrument Information Radiation: CuKa Wavelength: 1.5418 Filter: Ni Instrument(d): Guinier Standard: ThO2 Instrument(I): visual estimate I type: unknown Comments and Additional Information Source: Specimen from the Otway deposit, Nullagine district, Western Australia, Australia. Optical: B=1.78 Colour: Green Analysis: Microprobe analysis, recalculated to 100 after subtracting 8.6% pecoraite (wt.%): Ni 53.96, Mg 0.59, OH (calculated) 28.66, minor Cr, Mg, Fe, Cu (recalculation B); if the specific gravity is corrected for possible 13.34% water suggested by recalculation Ni 46.76, Mg 0.51, OH (calculated) 14.07, C O3 (calculated) 24.84, H2 O 13.34, minor Cr, Mg, Fe, Cu, then a value of 3.660 is obtained. Literature References General: Nickel, E., Berry. Can. Mineral. 19 315 (1981) Peak Data PeakList 2-Theta d(A) I(f) ( h k l ) Theta 1/(2d) 2pi/d n^2 12.111 7.3020 30.0 ( 1 1 0) 6.055 0.0685 0.8605 14.708 6.0180 5.0 ( 0 2 0) 7.354 0.0831 1.0441 17.589 5.0380 30.0 ( 1 2 0) 8.795 0.0992 1.2472 19.199 4.6190 40.0 ( 2 0 0) 9.600 0.1082 1.3603 24.299 3.6600 80.0 ( 1 3 0) 12.149 0.1366 1.7167 28.803 3.0970 20.0 ( 0 0 1) 14.402 0.1614 2.0288 29.746 3.0010 10.0 ( 0 4 0) 14.873 0.1666 2.0937 29.950 2.9810 10.0 ( 3 1 0) 14.975 0.1677 2.1077 30.462 2.9320 20.0 (-1 0 1) 15.231 0.1705 2.1430 31.316 2.8540 40.0 (-1 1 1) 15.658 0.1752 2.2015 32.655 2.7400 20.0 ( 3 2 0) 16.327 0.1825 2.2931 33.757 2.6530 10.0 (-1 2 1) 16.878 0.1885 2.3683 34.756 2.5790 100.0 (-2 0 1) 17.378 0.1939 2.4363 35.065 2.5570 90.0 ( 2 0 1) 17.532 0.1955 2.4572 35.655 2.5160 20.0 ( 2 4 0) 17.828 0.1987 2.4973 36.665 2.4490 10.0 ( 0 3 1) 18.332 0.2042 2.5656 41.147 2.1920 10.0 (-3 0 1) 20.573 0.2281 2.8664 42.422 2.1290 10.0 ( 2 5 0) 21.211 0.2349 2.9512 42.674 2.1170 5.0 21.337 0.2362 2.9680 43.145 2.0950 5.0 ( 1 4 1) 21.572 0.2387 2.9991 45.305 2.0000 10.0 ( 0 6 0) 22.652 0.2500 3.1416 49.640 1.8350 10.0 ( 2 6 0) 24.820 0.2725 3.4241 51.814 1.7630 20.0 ( 5 2 0) 25.907 0.2836 3.5639 52.682 1.7360 5.0 ( 2 5 1) 26.341 0.2880 3.6193 59.810 1.5450 30.0 ( 0 0 2) 29.905 0.3236 4.0668 59.981 1.5410 30.0 ( 6 0 0) 29.991 0.3245 4.0773 60.545 1.5280 40.0 ( 5 2 1) 30.272 0.3272 4.1120 68.537 1.3680 10.0 ( 6 4 0) 34.268 0.3655 4.5930 |
銀蟲 (小有名氣)
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