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Polymers of intrinsic microporosity (PIMs) formed by means of dioxane-forming reactions exhibit apparent Brunauer–Emmet–Teller (BET) specific surface areas of 500–
1000 m2 g1 depending on the structure of the monomers.Hyper-cross-linked polymers are another example of porous organic polymers that can display permanent porosity because of extensive chemical cross-links that prevent the polymer chains collapsing into dense solids. The simplest networks constructed from styrenic monomers have a wide
range of BET surface areas (100–2000 m2g1) that depend mainly on the degree of cross-linking and the monomers.Amorphous conjugated microporous polymers can be synthesized with BET surface areas in the range 500–1200 m2 g1 by means of Pd0/CuI-catalyzed Sonogashira cross-coupling.[19] Micropore distributions of these conjugated
poly(arylene ethynylene) materials could be controlled by means of the rigid node–strut topology, in particular by the average strut length,[19a,b] and this implies that order and crystallinity are not prerequisites for precise control over porosity of materials. These previous reports strongly suggest that selection of the right monomer is a critical factor to achieve synthetic porous organic polymers with high surface area and narrow pore size distribution.

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Polymers of intrinsic microporosity (PIMs) formed by means of dioxane-forming reactions exhibit apparent Brunauer–Emmet–Teller (BET) specific surface areas of 500–1000 m2 g1 depending on the structure of the monomers.
依靠單體結(jié)構(gòu)，通過(guò)二氧己環(huán)形成反應(yīng)生成的自具微孔聚合物(PIMs) ，展現(xiàn)出的明顯布BET(魯諾(Brunauer)、埃麥特(Emmet)和泰勒(Teller))比表面積達(dá) 500–1000 m2 g1.

Hyper-cross-linked polymers are another example of porous organic polymers that can display permanent porosity because of extensive chemical cross-links that prevent the polymer chains collapsing into dense solids.
多孔有機(jī)聚合物的另一個(gè)例子-超高交聯(lián)聚合物，因其廣泛的化學(xué)交聯(lián)反應(yīng)，有效的阻止了高分子鏈倒塌到稠密的固體組織中，因而它們能夠展現(xiàn)出永久的多孔性。

The simplest networks constructed from styrenic monomers have a wide
range of BET surface areas (100–2000 m2g1) that depend mainly on the degree of cross-linking and the monomers.
由苯乙烯構(gòu)建成的最簡(jiǎn)單的網(wǎng)絡(luò)，有廣泛的BET比表面積范圍（100–2000 m2g1），其主要取決于于交聯(lián)程度和單體分子。

Amorphous conjugated microporous polymers can be synthesized with BET surface areas in the range 500–1200 m2 g1 by means of Pd0/CuI-catalyzed Sonogashira cross-coupling.
Pd0/CuI作催化劑的薗頭偶合反應(yīng)，可以合成比表面積范圍為500–1200 m2 g1的非晶態(tài)共軛微孔聚合物。

[19] Micropore distributions of these conjugated poly(arylene ethynylene) materials could be controlled by means of the rigid node–strut topology, in particular by the average strut length,[19a,b] and this implies that order and crystallinity are not prerequisites for precise control over porosity of materials.
運(yùn)用剛性節(jié)點(diǎn)-支柱拓?fù)洌ㄓ绕涫�，平均支柱長(zhǎng)度[19a,b]），可以控制這些共軛聚合材料（亞芳基，亞乙炔基）的微孔分布。這表明結(jié)晶度和順序，不是準(zhǔn)確控制材料多孔性的先決條件。

These previous reports strongly suggest that selection of the right monomer is a critical factor to achieve synthetic porous organic polymers with high surface area and narrow pore size distribution.
此前這些報(bào)道，強(qiáng)烈建議，選擇正確的單體是決定性因數(shù)，決定著能否成功合成，高表面積，窄氣孔的多孔有機(jī)聚合物。

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