版塊導航: 正在加載中...

登錄注冊

應(yīng)《網(wǎng)絡(luò)安全法》要求，自2017年10月1日起，未進行實名認證將不得使用互聯(lián)網(wǎng)跟帖服務(wù)。為保障您的帳號能夠正常使用，請盡快對帳號進行手機號驗證，感謝您的理解與支持！

24小時熱門版塊排行榜

返回列表

大四寫論文

金蟲 (正式寫手)

應(yīng)助: 0 (幼兒園)
金幣: 648.8
散金: 1
沙發(fā): 1
帖子: 713
在線: 32.6小時
蟲號: 3550564
注冊: 2014-11-21
專業(yè): 高分子合成化學

[求助] 求翻譯這段話

Polymers of intrinsic microporosity (PIMs) formed by means of dioxane-forming reactions exhibit apparent Brunauer–Emmet–Teller (BET) specific surface areas of 500–
1000 m2 g1 depending on the structure of the monomers.Hyper-cross-linked polymers are another example of porous organic polymers that can display permanent porosity because of extensive chemical cross-links that prevent the polymer chains collapsing into dense solids. The simplest networks constructed from styrenic monomers have a wide
range of BET surface areas (100–2000 m2g1) that depend mainly on the degree of cross-linking and the monomers.Amorphous conjugated microporous polymers can be synthesized with BET surface areas in the range 500–1200 m2 g1 by means of Pd0/CuI-catalyzed Sonogashira cross-coupling.[19] Micropore distributions of these conjugated
poly(arylene ethynylene) materials could be controlled by means of the rigid node–strut topology, in particular by the average strut length,[19a,b] and this implies that order and crystallinity are not prerequisites for precise control over porosity of materials. These previous reports strongly suggest that selection of the right monomer is a critical factor to achieve synthetic porous organic polymers with high surface area and narrow pore size distribution.

回復(fù)此樓

» 猜你喜歡

287求調(diào)劑已經(jīng)有8人回復(fù)
一志愿西北大學，070300化學學碩，總分287，雙非一本，求調(diào)劑。已經(jīng)有4人回復(fù)
求調(diào)劑，一志愿:南京航空航天大學大學，080500材料科學與工程學碩，總分289分已經(jīng)有4人回復(fù)
085600材料與化工已經(jīng)有8人回復(fù)
材料與化工 322求調(diào)劑已經(jīng)有4人回復(fù)
藥學383 求調(diào)劑已經(jīng)有5人回復(fù)
一志愿蘇州大學材料求調(diào)劑，總分315（英一）已經(jīng)有5人回復(fù)
324求調(diào)劑已經(jīng)有4人回復(fù)
一志愿南昌大學，327分，材料與化工085600 已經(jīng)有8人回復(fù)
350求調(diào)劑已經(jīng)有5人回復(fù)

1樓 2015-03-20 09:54:06

已閱回復(fù)此樓關(guān)注TA 給TA發(fā)消息送TA紅花 TA的回帖

武漢一心一譯

捐助貴賓 (著名寫手)

翻譯EPI: 502
應(yīng)助: 8 (幼兒園)
金幣: 2283.1
散金: 5914
紅花: 32
帖子: 1665
在線: 321.9小時
蟲號: 3587652
注冊: 2014-12-10
性別: GG
專業(yè): 高分子合成化學

【答案】應(yīng)助回帖

商家已經(jīng)主動聲明此回帖可能含有宣傳內(nèi)容

★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★ ★
愛與雨下: 金幣+1 2015-03-20 22:27:00
大四寫論文: 金幣+40, ★★★很有幫助 2015-03-21 12:16:34

Polymers of intrinsic microporosity (PIMs) formed by means of dioxane-forming reactions exhibit apparent Brunauer–Emmet–Teller (BET) specific surface areas of 500–1000 m2 g1 depending on the structure of the monomers.
依靠單體結(jié)構(gòu)，通過二氧己環(huán)形成反應(yīng)生成的自具微孔聚合物(PIMs) ，展現(xiàn)出的明顯布BET(魯諾(Brunauer)、埃麥特(Emmet)和泰勒(Teller))比表面積達 500–1000 m2 g1.

Hyper-cross-linked polymers are another example of porous organic polymers that can display permanent porosity because of extensive chemical cross-links that prevent the polymer chains collapsing into dense solids.
多孔有機聚合物的另一個例子-超高交聯(lián)聚合物，因其廣泛的化學交聯(lián)反應(yīng)，有效的阻止了高分子鏈倒塌到稠密的固體組織中，因而它們能夠展現(xiàn)出永久的多孔性。

The simplest networks constructed from styrenic monomers have a wide
range of BET surface areas (100–2000 m2g1) that depend mainly on the degree of cross-linking and the monomers.
由苯乙烯構(gòu)建成的最簡單的網(wǎng)絡(luò)，有廣泛的BET比表面積范圍（100–2000 m2g1），其主要取決于于交聯(lián)程度和單體分子。

Amorphous conjugated microporous polymers can be synthesized with BET surface areas in the range 500–1200 m2 g1 by means of Pd0/CuI-catalyzed Sonogashira cross-coupling.
Pd0/CuI作催化劑的薗頭偶合反應(yīng)，可以合成比表面積范圍為500–1200 m2 g1的非晶態(tài)共軛微孔聚合物。

[19] Micropore distributions of these conjugated poly(arylene ethynylene) materials could be controlled by means of the rigid node–strut topology, in particular by the average strut length,[19a,b] and this implies that order and crystallinity are not prerequisites for precise control over porosity of materials.
運用剛性節(jié)點-支柱拓撲（尤其是，平均支柱長度[19a,b]），可以控制這些共軛聚合材料（亞芳基，亞乙炔基）的微孔分布。這表明結(jié)晶度和順序，不是準確控制材料多孔性的先決條件。

These previous reports strongly suggest that selection of the right monomer is a critical factor to achieve synthetic porous organic polymers with high surface area and narrow pore size distribution.
此前這些報道，強烈建議，選擇正確的單體是決定性因數(shù)，決定著能否成功合成，高表面積，窄氣孔的多孔有機聚合物。

贊一下

回復(fù)此樓

2樓2015-03-20 16:42:56