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Conclusions Ultimate goals of this investigation were the synthesis of a series of organosoluble and optically active aromatic PAs that possess several advanced characteristics such as optical activity, possession of wholly aromatic backbone and organosolubility under green condition using imidazolium type ILs. This environmentally friendly green technique is a safe, fast, high yielding, economical and simple manipulation route, which avoids the usage of volatile organic solvents and catalyst. Optical activity of resulting PAs, make them the potentially useful candidates as the new chiral stationary phases in HPLC techniques. Wholly aromatic backbones of PAs provide some superior properties such as stability toward thermal shocks, chemical resistances and mechanical strength and at last, organosolubility of PAs removes the processing difficulties which regularly are associated with handing out of the wholly aromatic PAs. Potential applications of amino acid-based polymers include drug delivery agent, chiral stationary phases for resolution of enantiomers in chromatographic techniques and biomaterials. |
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Conclusions 結(jié)論 Ultimate goals of this investigation were the synthesis of a series of organosoluble and optically active aromatic PAs that possess several advanced characteristics such as optical activity, possession of wholly aromatic backbone and organosolubility under green condition using imidazolium type ILs. 本實(shí)驗(yàn)的最終目標(biāo),就是合成一系列有機(jī)可溶性和光學(xué)活性的芳香族對氨基水楊酸,它們具有幾項(xiàng)優(yōu)勢特點(diǎn),例如較高的光學(xué)活性,擁有完全的芳香的支柱,以及在綠色環(huán)境下的有機(jī)可溶性(運(yùn)用咪唑鎓鹽性室溫熔鹽)。 This environmentally friendly green technique is a safe, fast, high yielding, economical and simple mnipulation route, which avoids the usage of volatile organic solvents and catalyst. 這項(xiàng)綠色技術(shù)對環(huán)境無害,且安全,高效,產(chǎn)出率高,經(jīng)濟(jì),又易于操作,同時(shí)避免了使用揮發(fā)性有機(jī)溶劑和催化劑。 Optical activity of resulting PAs, make them the potentially useful candidates as the new chiral stationary phases in HPLC techniques. 由于生成的對氨基水楊酸,具有光學(xué)活性,使得它們可能成為新型的手性固定相,在高效液相色譜技術(shù)中發(fā)揮作用。 Wholly aromatic backbones of PAs provide some superior properties such as stability toward thermal shocks, chemical resistances and mechanical strength and at last, organosolubility of PAs removes the processing difficulties which regularly are associated with handing out of the wholly aromatic PAs. 由于具有完全的芳香支柱,使得對氨基水楊酸具有一些優(yōu)勢特點(diǎn),例如抗熱沖擊性,耐化學(xué)性,高力學(xué)強(qiáng)度,以及有機(jī)可溶性(因?yàn)檫@一點(diǎn),在分發(fā)完全芳香族對氨基水楊酸的過程中,通常遇到的技術(shù)難點(diǎn)不復(fù)存在)。 Potential applications of amino acid-based polymers include drug delivery agent, chiral stationary phases for resolution of enantiomers in chromatographic techniques and biomaterials. 氨基酸類聚合物的潛在用途包括:作為藥物載體,作為色譜技術(shù)和生物材料中,拆分對映體的手性固定相。 |
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