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chendy6822木蟲 (知名作家)
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[求助]
請幫助翻譯兩句話(中譯英)
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第二種提法沒有嚴格的推導,而且,活化分子的最低能量實際上是分子水平的微觀量, 而反應物平均能量是宏觀物理量,用兩個不同性質的量來定義一個通過實驗測出的宏觀物理量, 顯然不夠準確。 第三種提法是采用Tolman的提法,是按照統(tǒng)計力學觀點,從理論上嚴格推導出來的。 |
禁蟲 (正式寫手)
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木蟲 (小有名氣)
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The second formulation is not strictly derived. Moreover, the minimum energy of activated molecules is actually the microscopic quantity in the molecular level while the average energy of reactants is the macro-physical quantity. So obviously, it is not accurate enough to define an macroscopic physical quantity obtained by experiments by two different types of capacity. However, the third formulation is strictly derived from theory based on views of statistical mechanics according to Tolman's formulation. |
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