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smth木蟲 (小有名氣)
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[求助]
幫忙翻譯成英文
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| 傳統(tǒng)合成苯并噁唑的方法是以鄰氨基苯酚與羧酸、酰氯、酯和醛等反應(yīng)獲得，所用到的催化劑大多是Pd、Au或Ag等貴重金屬的絡(luò)合物。目前，以鄰氨基苯酚和腈為原料來構(gòu)建苯并噁唑衍生物鮮見文獻報道，本文采用廉價的三氟甲基磺酸銅為催化劑，從鄰氨基苯酚與腈出發(fā)一步法構(gòu)建了苯并噁唑衍生物，反應(yīng)條件溫和，對空氣不敏感且無需惰性氣體保護。該方法適應(yīng)范圍廣，不論是芳香腈還是脂肪腈都可以順利反應(yīng)。 |
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liu2004m
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【答案】應(yīng)助回帖
| The traditional synthesis of benzoxazole method is based on the o-aminophenol with carboxylic acid chloride, esters and aldehydes, such as reaction, the catalyst used in most of the complexes of precious metals such as Pd, Au or Ag. At present, the benzo-o-aminophenol and nitrile as a raw material to build the benzoxazole derivatives uncommon reported in the literature, this article uses cheap trifluoromethyl sulfonic acid copper as a catalyst, one step starting from o-aminophenol and Nitrile constructed oxazole derivatives, mild reaction conditions, is not sensitive to the air without inert gas protection. The method is suitable for a wide range of both aromatic nitriles or fat nitrile can be smoothly reaction. |
2樓2012-04-10 13:02:33
smth
木蟲 (小有名氣)
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3樓2012-04-10 13:42:35
wzcrazy
至尊木蟲 (著名寫手)
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【答案】應(yīng)助回帖
| The traditional synthesis of benzoxazole method is based on the reaction of ortho-aminophenol with carboxylic acid,acyl , ester and aldehyde , the kind of catalyst used are mostly precious metal complex Pd, Au or Ag of etc.At present, there is little detailed information about structuring benzoxazole derivatives with ortho-aminophenol and nitrile as raw material,use cheaper material like trifluoromethyl sulfonic acid copper as catalyst adop one-step method to structure benzoxazole derivatives with ortho-aminophenol and nitrile，the reaction condition is mild,not sensitive to the air ,and no needto protecede by inert gas.The method is suitable for a wide range ,no matter aromatic nitriles or fat nitrile can be smoothly reaction. |
4樓2012-04-10 14:36:22
_▕若¨|相依
木蟲 (正式寫手)
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【答案】應(yīng)助回帖
| The traditional method of the synthesis of benzoxazole is based on the reaction of ortho-aminophenol with carboxylic acid,acyl , ester and aldehyde , the catalyst used in above reactions mostly is precious metal complex like Pd, Au or Ag etc.At present, there is little detailed information about structuring benzoxazole derivatives with ortho-aminophenol and nitrile as raw material.In this article,we used cheap material like trifluoromethyl sulfonic acid copper as catalyst,and construced benzoxazole derivatives by one step with ortho-aminophenol and nitrile to start ，the reaction condition is mild,not sensitive to the air ,and no need to protecected by inert gas.The method is suitable for a wide range ,no matter aromatic nitriles or fatty nitrile can be smoothly reaction.對翻譯有興趣才翻譯的，借助了詞典，專業(yè)名詞翻譯可能不是很專業(yè)，你參考一下吧，嘿嘿 |
5樓2012-04-11 22:51:16
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