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sunburst8796木蟲 (小有名氣)
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[求助]
有懂“Inner Filter Effect”的么,被審稿人搞懵了!
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本人最近投稿一篇,審稿人有三個,有兩個審稿人意見都很好,提了一些不是問題的問題,只有一個審稿人很難搞,按照意見修改后,另兩個審稿人同意接受,這個審稿人仍然不滿意,而且加了感嘆號,可見回答得多不滿意,可是問題實在很讓人迷惑,好像是說我這個分析是基于inner filter effects,但不能用Stern-Volmer equation分析,他認(rèn)為inner filter effects的特定分析模型不是這個,本人對這個確實不太懂,有沒有高手了解inner filter effects該用什么分析才準(zhǔn)確,望高手指點,審稿意見如下: 第一次的“This paper presents a study about a sensor for catecholics based on a mechanism called by the authors as an external quenching. The authors analysed the called "external quenching" using a Stern-Volmer equation. This paper has a critical problem which is the interpretation of the mechanism of "quenching". Indeed, this mechanism is the well known fluorescence inner filter effects which have a specific model formulation. Analyzing the observed fluorescence intensity variation using a Stern-Volmer is probably not useful because there is no physical meaning.” 第二次的“The authors have made some improvements in the paper. However there is still a critical problem about the model that they used for the decreasing of fluorescence intensity linearization. Indeed, the Stern-Volmer model corresponds to a quenching mechanism and not to an inner-filter effect decreasing of fluorescence intensity. The application of a Stern-Vomer model in this paper is of empirical nature! For this last phenomenon there are several models in the literature that should be used.” |
木蟲 (小有名氣)
專家顧問 (著名寫手)
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專家經(jīng)驗: +19 |
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Page 4 in the following material: http://www.rsc.org/suppdata/cc/b9/b902216c/b902216c.pdf Hope it is helpful to you. |
木蟲 (小有名氣)
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