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want-you銅蟲 (初入文壇)
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[求助]
文獻有一段看不懂,求助各位
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Dark-field optical microspectroscopy was used to detect changes in the individual nanoparticle LSPR scattering spectrum upon resonant laser illumination . The measured LSPR spectrum in air was found to peak at 563 nm. When the microchamber was filled with DI water with a temperature of 20 °C, the LSPR was observed to redshift to 598 nm. The redshift of 35 nm is in good agreement with the redshift obtained from a Mie calculation for the same particle embedded in air compared with that in water at 20 °C (ε = 1.778). During laser illumination while the nanoparticle was surrounded by water, however, the LSPR was observed to blueshift to 581 nm.The observed shift implies a decreased refractive index of the medium directly surrounding the nanoparticle, which we interpret as resulting from a water vapor envelope surrounding the nanoparticle. 這是在看的論文中的一段,有一些看不懂的地方。這三次測量都應該是在光照條件下吧?為什么第二次沒有產(chǎn)生包覆粒子的氣泡? [ Last edited by want-you on 2013-10-10 at 14:45 ] |
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