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lihuihui520新蟲 (小有名氣)
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[求助]
如何對審稿人的問題進行合理解釋? 已有3人參與
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晶體學(xué)數(shù)據(jù)問題,求助高手幫忙分析,小女子萬分感激: 1. We see from the CIF that there are 2 Uiso/Uij restrained atom sites, 3 distance or angle restraints and 15 least-squares restraints used in the refinement. So that the reader can be fully aware of what was done to generate the reported models, we should be told - at least in the "_refine_special_details" section of the CIF or in an ESI text - exactly what these restraints were and why they were necessary. [An easy way to show what restraints were employed (but not why they were needed) is to include the relevant lines from the SHELXL. ins file in the "_refine_special_details" section of the CIF. This should now be done.] 這是我在解決錯誤時,所加的命令: simu 0.01 0.02 3.8 $n simu 0.01 0.02 3.8 $c delu 0.002 C40 DFIX c39 n8 2.65 ISOR 0.001 c39 C40 dfix N8 C40 1.1 dfix C39 C40 1.4 2. Where there is crystallographically imposed symmetry in these structures we should be explicitly told about this in the appropriate descriptive text. 這個是在哪里能看到提議的對稱性? |
新蟲 (小有名氣)
專家顧問 (文壇精英)
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專家經(jīng)驗: +1066 |
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第一個問題,你需要在CIF文件_refine_special_details 加上你的這些個限制性精修的命令,然后在ESI里面解釋為什么使用這些個命令 第二個關(guān)于結(jié)構(gòu)對稱性的問題,這個需要具體結(jié)合結(jié)構(gòu)來看,比如某個原子處于二重軸,或者鏡面什么的 發(fā)自小木蟲Android客戶端 |

用戶注銷 (知名作家)
精修問題可私信
鐵桿木蟲 (著名寫手)
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