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yyj1金蟲 (初入文壇)
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[求助]
幾道題目,求大神幫助
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題目全是英文的,我不太會翻譯![]() 大概是求molar absorptivity (莫耳吸光度) 還有 equilibrium constant (平衡常數(shù)) ![]() Reaction: 2CrO4 + 2H+ <--> Cr2O72- + H2O The following absorbance data were obtained for a 2 x 10-4M solution of K2Cr2O7 in H2SO4 and NaOH. Measurement were made at wavelengths of 348nm and 372 nm, with 1cm cells. K2Cr2O7 (2mL) + H2SO4 (0.2mL): A(348) =0.466, A(372) = 0.298 K2Cr2O7(2mL) + H2O(7.5mL) + NaOH(0.5mL): A(348) = 0.197, A(372) = 0.372 In the H2SO4 solution, most of the chromium are in the dichromate form (Cr2O7), and the concentration of the solution is about 1.8 x 10-4M. In the NaOH solution, all of the chromium are in the chromate form, and the concentration of the solution = 8 x 10-5M. Questions a) Find the molar absorptivities for CrO4 and Cr2O7 at 348nm, and 372nm. b) i) Calculate the equilibrium constant for the reaction, if a 5mL of pH 4.5 buffer containing 5mL of 2x10-4M KCr2O7 exhibits an absorbance of 0.314 at 348nm, and 0.222 at 372nm. (1cm cells). ii) Calculate the equilibrium constant at pH 5.5, and 5.8. pH 5.5: A(348) = 0.359, A(372) = 0.381 pH 5.8: A(348) = 0.382, A(372) = 0.468 我已經(jīng)為這幾道題已經(jīng)頭疼了三天了 ![]() 無論怎么算,算出來的結果都怪怪的 ![]() 有誰愿意幫幫我呢另外,我是金幣不多,給不起太多賞金 |
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